1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide
In the title compound, C16H11F3N4OS, the dihedral angle between the aromatic ring systems is 69.15 (10)°. Intramolecular N—H...N and N—H...O hydrogen bonds generate S(5) and S(6) rings, respectively. A short N—H...F contact also oc...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681003343X |
| _version_ | 1819280165174247424 |
|---|---|
| author | Muhammad Ramzan Humayun Pervez Muhammad Yaqub M. Nawaz Tahir |
| author_facet | Muhammad Ramzan Humayun Pervez Muhammad Yaqub M. Nawaz Tahir |
| author_sort | Muhammad Ramzan |
| collection | DOAJ |
| description | In the title compound, C16H11F3N4OS, the dihedral angle between the aromatic ring systems is 69.15 (10)°. Intramolecular N—H...N and N—H...O hydrogen bonds generate S(5) and S(6) rings, respectively. A short N—H...F contact also occurs. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(8) loops. The dimers are linked by N—H...F hydrogen bonds, forming polymeric chains propagating in [100]. π–π interactions also exist between the centroids of the benzene rings of the 2-oxoindoline group at a distance of 3.543 (3) Å and a short C=O...π contact occurs. Two F atoms of the trifluoromethyl group are disordered over two sets of sites in a 0.517 (8):0.483 (8) ratio. |
| first_indexed | 2024-12-24T00:39:27Z |
| format | Article |
| id | doaj.art-77f5d420cc3c475f97a86eec0e124cf1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:27Z |
| publishDate | 2010-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-77f5d420cc3c475f97a86eec0e124cf12022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669o2387o238710.1107/S160053681003343X1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazideMuhammad RamzanHumayun PervezMuhammad YaqubM. Nawaz TahirIn the title compound, C16H11F3N4OS, the dihedral angle between the aromatic ring systems is 69.15 (10)°. Intramolecular N—H...N and N—H...O hydrogen bonds generate S(5) and S(6) rings, respectively. A short N—H...F contact also occurs. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(8) loops. The dimers are linked by N—H...F hydrogen bonds, forming polymeric chains propagating in [100]. π–π interactions also exist between the centroids of the benzene rings of the 2-oxoindoline group at a distance of 3.543 (3) Å and a short C=O...π contact occurs. Two F atoms of the trifluoromethyl group are disordered over two sets of sites in a 0.517 (8):0.483 (8) ratio.http://scripts.iucr.org/cgi-bin/paper?S160053681003343X |
| spellingShingle | Muhammad Ramzan Humayun Pervez Muhammad Yaqub M. Nawaz Tahir 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide Acta Crystallographica Section E |
| title | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide |
| title_full | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide |
| title_fullStr | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide |
| title_full_unstemmed | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide |
| title_short | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethyl)phenyl]thiosemicarbazide |
| title_sort | 1 2 oxoindolin 3 ylidene 4 2 trifluoromethyl phenyl thiosemicarbazide |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681003343X |
| work_keys_str_mv | AT muhammadramzan 12oxoindolin3ylidene42trifluoromethylphenylthiosemicarbazide AT humayunpervez 12oxoindolin3ylidene42trifluoromethylphenylthiosemicarbazide AT muhammadyaqub 12oxoindolin3ylidene42trifluoromethylphenylthiosemicarbazide AT mnawaztahir 12oxoindolin3ylidene42trifluoromethylphenylthiosemicarbazide |