Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System

The reported patent-pending system comprises a novel biohydrogen reactor with a gravity settler for decoupling of SRT from HRT. The biohydrogenator was operated for 100 days at 37 °C, hydraulic retention time 8 h and solids retention time ranging from 2.2–2.5 days. The feed was a corn-syrup waste ge...

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Main Authors: George Nakhla, Hisham Hafez, Hesham El Naggar
Format: Article
Language:English
Published: MDPI AG 2009-06-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/2/2/445/
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author George Nakhla
Hisham Hafez
Hesham El Naggar
author_facet George Nakhla
Hisham Hafez
Hesham El Naggar
author_sort George Nakhla
collection DOAJ
description The reported patent-pending system comprises a novel biohydrogen reactor with a gravity settler for decoupling of SRT from HRT. The biohydrogenator was operated for 100 days at 37 °C, hydraulic retention time 8 h and solids retention time ranging from 2.2–2.5 days. The feed was a corn-syrup waste generated as a byproduct from an industrial facility for bioethanol production located in southwestern Ontario, Canada. The system was initially started up with a synthetic feed containing glucose at concentration of 8 g/L and other essential inorganics. Anaerobicaly-digested sludge from the St. Mary’s wastewater treatment plant (St. Mary, Ontario, Canada) was used as the seed, and was heat treated at 70 °C for 30 min to inhibit methanogens. After 10 days, when the hydrogen production was steady, the corn-syrup waste was introduced to the system. Glucose was the main constituent in the corn-syrup; its concentration was varied over a period of 90 days from 8 to 25 g/L. The change in glucose concentration was used to study the impact of variable organic loading on the stability of hydrogen production in the biohydrogenator. Hydrogen production rate increased from 10 L H2/L·d to 34 L H2/L·d with the increase of organic loading rate (OLR) from 26 to 81 gCOD/L·d, while a maximum hydrogen yield of 430 mL H2/gCOD was achieved in the system with an overall average of 385 mL H2/gCOD.
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spelling doaj.art-77fade2e9d5d48798552d2edebdfd1912022-12-22T03:59:24ZengMDPI AGEnergies1996-10732009-06-012244545510.3390/en20200445Biological Hydrogen Production from Corn-Syrup Waste Using a Novel SystemGeorge NakhlaHisham HafezHesham El NaggarThe reported patent-pending system comprises a novel biohydrogen reactor with a gravity settler for decoupling of SRT from HRT. The biohydrogenator was operated for 100 days at 37 °C, hydraulic retention time 8 h and solids retention time ranging from 2.2–2.5 days. The feed was a corn-syrup waste generated as a byproduct from an industrial facility for bioethanol production located in southwestern Ontario, Canada. The system was initially started up with a synthetic feed containing glucose at concentration of 8 g/L and other essential inorganics. Anaerobicaly-digested sludge from the St. Mary’s wastewater treatment plant (St. Mary, Ontario, Canada) was used as the seed, and was heat treated at 70 °C for 30 min to inhibit methanogens. After 10 days, when the hydrogen production was steady, the corn-syrup waste was introduced to the system. Glucose was the main constituent in the corn-syrup; its concentration was varied over a period of 90 days from 8 to 25 g/L. The change in glucose concentration was used to study the impact of variable organic loading on the stability of hydrogen production in the biohydrogenator. Hydrogen production rate increased from 10 L H2/L·d to 34 L H2/L·d with the increase of organic loading rate (OLR) from 26 to 81 gCOD/L·d, while a maximum hydrogen yield of 430 mL H2/gCOD was achieved in the system with an overall average of 385 mL H2/gCOD.http://www.mdpi.com/1996-1073/2/2/445/biohydrogenatorcorn-syruporganic loading rate
spellingShingle George Nakhla
Hisham Hafez
Hesham El Naggar
Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System
Energies
biohydrogenator
corn-syrup
organic loading rate
title Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System
title_full Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System
title_fullStr Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System
title_full_unstemmed Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System
title_short Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System
title_sort biological hydrogen production from corn syrup waste using a novel system
topic biohydrogenator
corn-syrup
organic loading rate
url http://www.mdpi.com/1996-1073/2/2/445/
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