Built-in voltage in thin ferroelectric PbTiO3 films: the effect of electrostatic boundary conditions

We have studied the built-in voltage in heterostructures composed of ferroelectric PbTiO _3 and dielectric spacers of SrTiO _3 , grown on SrTiO _3 substrates with SrRuO _3 bottom electrodes. We used piezoresponse force microscopy to determine the domain structure of the samples and perform local swi...

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Bibliographic Details
Main Authors: Céline Lichtensteiger, Christian Weymann, Stéphanie Fernandez-Pena, Patrycja Paruch, Jean-Marc Triscone
Format: Article
Language:English
Published: IOP Publishing 2016-01-01
Series:New Journal of Physics
Subjects:
Online Access:https://doi.org/10.1088/1367-2630/18/4/043030
Description
Summary:We have studied the built-in voltage in heterostructures composed of ferroelectric PbTiO _3 and dielectric spacers of SrTiO _3 , grown on SrTiO _3 substrates with SrRuO _3 bottom electrodes. We used piezoresponse force microscopy to determine the domain structure of the samples and perform local switching experiments. By increasing the thickness of the SrTiO _3 spacer layers, we were able to tune the polarization configuration in the PbTiO _3 films by gradually going from a monodomain configuration to a polydomain one. The built-in voltage was found to be linked to the choice of electrodes and to the thickness of the spacer layer. The stability of artificially poled regions was also affected, with a faster back-switching for the samples with the thicker SrTiO _3 spacers. We have additionally compared samples with and without a top SrRuO _3 electrode, showing that a top electrode layer results in a stronger built-in voltage, responsible for a preferential monodomain configuration and a very fast back-switching of artificially poled regions.
ISSN:1367-2630