Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant

Polyurethane material is used as an interior finish and wall cavity insulation. Flame-retardant products may be used for ignition, flame diffusion, and heat-release blocking. A large-scale test was conducted to understand the flame propagation characteristics of polyurethane with the addition of a f...

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Main Authors: Ji Hun Choi, Seung Un Chae, Euy Hong Hwang, Don Mook Choi
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Fire
Subjects:
Online Access:https://www.mdpi.com/2571-6255/5/4/105
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author Ji Hun Choi
Seung Un Chae
Euy Hong Hwang
Don Mook Choi
author_facet Ji Hun Choi
Seung Un Chae
Euy Hong Hwang
Don Mook Choi
author_sort Ji Hun Choi
collection DOAJ
description Polyurethane material is used as an interior finish and wall cavity insulation. Flame-retardant products may be used for ignition, flame diffusion, and heat-release blocking. A large-scale test was conducted to understand the flame propagation characteristics of polyurethane with the addition of a flame retardant. The fire propagation properties and fire risks of four commonly used polyurethane materials were examined using three tests. Specifically, ignition properties, flame propagation behavior, and flashover occurrence were probed using full-scale tests, while heat release and fire characteristics were examined using cone calorimeter tests, and the toxicity of gaseous combustion products was assessed using gas toxicity tests. PIR F and PIR B, which contained flame retardants, featured slow flame propagation and a long-lasting residual flame, and PIR F released HCl and Br<sub>2</sub> on combustion. Full-scale tests revealed that although external flame propagation was always accompanied by flashover, irrespective of whether the flame retardant was present, a delay or blockage of energy transfer to the inside was observed for flame-retardant-containing specimens. Apart from checking the safety at the material level, the importance of identifying the actual fire characteristics through a full-scale test was confirmed.
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spelling doaj.art-7818160e0f11476cb9e6152e65e38cab2023-12-03T13:38:20ZengMDPI AGFire2571-62552022-07-015410510.3390/fire5040105Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame RetardantJi Hun Choi0Seung Un Chae1Euy Hong Hwang2Don Mook Choi3Department of Equipment System, Fire Protection Engineering, Gachon University, 1342, Seongnam-daero, Sujeong-gu, Seongnam-si 13120, KoreaDepartment of Fire Safety Research, Korea Institute of Civil Engineering and Building Technology, 64, Mado-ro 182beon-gil, Mado-myeon, Hwaseong-si 18544, KoreaDepartment of Equipment System, Fire Protection Engineering, Gachon University, 1342, Seongnam-daero, Sujeong-gu, Seongnam-si 13120, KoreaDepartment of Equipment System, Fire Protection Engineering, Gachon University, 1342, Seongnam-daero, Sujeong-gu, Seongnam-si 13120, KoreaPolyurethane material is used as an interior finish and wall cavity insulation. Flame-retardant products may be used for ignition, flame diffusion, and heat-release blocking. A large-scale test was conducted to understand the flame propagation characteristics of polyurethane with the addition of a flame retardant. The fire propagation properties and fire risks of four commonly used polyurethane materials were examined using three tests. Specifically, ignition properties, flame propagation behavior, and flashover occurrence were probed using full-scale tests, while heat release and fire characteristics were examined using cone calorimeter tests, and the toxicity of gaseous combustion products was assessed using gas toxicity tests. PIR F and PIR B, which contained flame retardants, featured slow flame propagation and a long-lasting residual flame, and PIR F released HCl and Br<sub>2</sub> on combustion. Full-scale tests revealed that although external flame propagation was always accompanied by flashover, irrespective of whether the flame retardant was present, a delay or blockage of energy transfer to the inside was observed for flame-retardant-containing specimens. Apart from checking the safety at the material level, the importance of identifying the actual fire characteristics through a full-scale test was confirmed.https://www.mdpi.com/2571-6255/5/4/105polyurethane resinpolyisocyanurate resinflame propagation characteristicsfire riskreal fire testfoam
spellingShingle Ji Hun Choi
Seung Un Chae
Euy Hong Hwang
Don Mook Choi
Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant
Fire
polyurethane resin
polyisocyanurate resin
flame propagation characteristics
fire risk
real fire test
foam
title Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant
title_full Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant
title_fullStr Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant
title_full_unstemmed Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant
title_short Fire Propagation Characteristics and Fire Risks of Polyurethanes: Effects of Material Type (Foam & Board) and Added Flame Retardant
title_sort fire propagation characteristics and fire risks of polyurethanes effects of material type foam board and added flame retardant
topic polyurethane resin
polyisocyanurate resin
flame propagation characteristics
fire risk
real fire test
foam
url https://www.mdpi.com/2571-6255/5/4/105
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