Comparison of Gas Sensing Properties of Reduced Graphene Oxide Obtained by Two Different Methods

In this study, the sensitivity of reduced graphene oxide structures (rGO) to the action of selected gases (especially hydrogen, but also nitrogen dioxide and ammonia) was examined. Two sensing structures, based on rGO structures, obtained by different methods of oxidation (the modified Hummers, and...

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Bibliographic Details
Main Authors: Sabina Drewniak, Marcin Procek, Roksana Muzyka, Tadeusz Pustelny
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/20/11/3175
Description
Summary:In this study, the sensitivity of reduced graphene oxide structures (rGO) to the action of selected gases (especially hydrogen, but also nitrogen dioxide and ammonia) was examined. Two sensing structures, based on rGO structures, obtained by different methods of oxidation (the modified Hummers, and the modified Tour’s method respectively), were investigated. We show here that the method used for the oxidation of rGO influences the sensitivity of the sensing structure during contact with various gaseous atmospheres. We performed our experiments in the atmosphere, containing hydrogen in a concentration range from 0 to 4% in nitrogen or synthetic air, both in dry and wet conditions. The temperature range was from 50 °C to 190 °C. Finally, we checked how the resistance of the samples changes when the other gases (NO<sub>2</sub>, NH<sub>3</sub>) appear in tested gas mixtures. The gas investigations were supplemented by the characterization of rGOs materials using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and N<sub>2</sub> sorption method.
ISSN:1424-8220