Synthesis, Characterization and Gas Sensing Properties of Ag@α-Fe2O3 Core–Shell Nanocomposites

Ag@α-Fe2O3 nanocomposite having a core–shell structure was synthesized by a two-step reduction-sol gel approach, including Ag nanoparticles synthesis by sodium borohydride as the reducing agent in a first step and the subsequent mixing with a Fe+3 sol for α-Fe2O3 coating. The synthesized Ag@α-Fe2O3...

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Bibliographic Details
Main Authors: Ali Mirzaei, Kamal Janghorban, Babak Hashemi, Anna Bonavita, Maryam Bonyani, Salvatore Gianluca Leonardi, Giovanni Neri
Format: Article
Language:English
Published: MDPI AG 2015-05-01
Series:Nanomaterials
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Online Access:http://www.mdpi.com/2079-4991/5/2/737
Description
Summary:Ag@α-Fe2O3 nanocomposite having a core–shell structure was synthesized by a two-step reduction-sol gel approach, including Ag nanoparticles synthesis by sodium borohydride as the reducing agent in a first step and the subsequent mixing with a Fe+3 sol for α-Fe2O3 coating. The synthesized Ag@α-Fe2O3 nanocomposite has been characterized by various techniques, such as SEM, TEM and UV-Vis spectroscopy. The electrical and gas sensing properties of the synthesized composite towards low concentrations of ethanol have been evaluated. The Ag@α-Fe2O3 nanocomposite showed better sensing characteristics than the pure α-Fe2O3. The peculiar hierarchical nano-architecture and the chemical and electronic sensitization effect of Ag nanoparticles in Ag@α-Fe2O3 sensors were postulated to play a key role in modulating gas-sensing properties in comparison to pristine α-Fe2O3 sensors.
ISSN:2079-4991