Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea
In the title compound, 2C5H12N+·SO42−·2C3H8N2S, the C=S groups of the two independent 1,3-dimethylurea molecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bonded to the sulfate by...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017004820 |
| _version_ | 1819003056000335872 |
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| author | Cindy Döring Julian F. D. Lueck Peter G. Jones |
| author_facet | Cindy Döring Julian F. D. Lueck Peter G. Jones |
| author_sort | Cindy Döring |
| collection | DOAJ |
| description | In the title compound, 2C5H12N+·SO42−·2C3H8N2S, the C=S groups of the two independent 1,3-dimethylurea molecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bonded to the sulfate by N—H...O and C—H...O interactions. The 1,3-dimethylurea molecules are also hydrogen bonded to sulfate O atoms, and project outwards from the ribbon parallel to the b axis. |
| first_indexed | 2024-12-20T23:14:55Z |
| format | Article |
| id | doaj.art-783e619cc13144f486bc67ae65213089 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:14:55Z |
| publishDate | 2017-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-783e619cc13144f486bc67ae652130892022-12-21T19:23:39ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-05-0173565165310.1107/S2056989017004820hg5484Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthioureaCindy Döring0Julian F. D. Lueck1Peter G. Jones2Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, GermanyInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, GermanyInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, GermanyIn the title compound, 2C5H12N+·SO42−·2C3H8N2S, the C=S groups of the two independent 1,3-dimethylurea molecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bonded to the sulfate by N—H...O and C—H...O interactions. The 1,3-dimethylurea molecules are also hydrogen bonded to sulfate O atoms, and project outwards from the ribbon parallel to the b axis.http://scripts.iucr.org/cgi-bin/paper?S2056989017004820crystal structurehydrogen bondspiperidinesulfatedimethylthiourea |
| spellingShingle | Cindy Döring Julian F. D. Lueck Peter G. Jones Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bonds piperidine sulfate dimethylthiourea |
| title | Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea |
| title_full | Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea |
| title_fullStr | Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea |
| title_full_unstemmed | Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea |
| title_short | Crystal structure of the 1:2 adduct of bis(piperidinium) sulfate and 1,3-dimethylthiourea |
| title_sort | crystal structure of the 1 2 adduct of bis piperidinium sulfate and 1 3 dimethylthiourea |
| topic | crystal structure hydrogen bonds piperidine sulfate dimethylthiourea |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017004820 |
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