Stepwise Utilization Process to Recover Valuable Components from Copper Slag

Waste copper slag is a typical hazardous solid waste containing a variety of valuable elements and has not been effectively disposed of so far. In this paper, a stepwise extraction process was proposed to recover valuable elements (copper, iron, lead and zinc) from waste copper slag. The specific pr...

Full description

Bibliographic Details
Main Authors: Siwei Li, Zhengqi Guo, Jian Pan, Deqing Zhu, Tao Dong, Shenghu Lu
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/11/2/211
_version_ 1797396251568766976
author Siwei Li
Zhengqi Guo
Jian Pan
Deqing Zhu
Tao Dong
Shenghu Lu
author_facet Siwei Li
Zhengqi Guo
Jian Pan
Deqing Zhu
Tao Dong
Shenghu Lu
author_sort Siwei Li
collection DOAJ
description Waste copper slag is a typical hazardous solid waste containing a variety of valuable elements and has not been effectively disposed of so far. In this paper, a stepwise extraction process was proposed to recover valuable elements (copper, iron, lead and zinc) from waste copper slag. The specific procedures are as follows: (1) A flotation process was adopted to enrich copper, and when the copper grade in the flotation concentrate was 21.50%, the copper recovery rate was 77.78%. (2) The flotation tailings were pelletized with limestone, then the green pellets were reduced, and the magnetic separation process was carried out. When the iron and copper grades in the magnetic concentrate were 90.21% Fe and 0.4% Cu, 91.34% iron and 83.41% copper were recovered, respectively. (3) Non-magnetic tailings were mixed with clinker and standard sand to produce common Portland cement. Several products were obtained from the waste copper slag through the proposed process: flotation concentrate, measured 21.50% Cu; magnetic concentrate, containing 90.21% TFe and 0.4% Cu; direct reduction dust, including 65.17% ZnO and 2.66% PbO; common Portland cement for building construction. The comprehensive utilization method for waste copper slag achieved zero tailing and has great potential for practical application.
first_indexed 2024-03-09T00:47:42Z
format Article
id doaj.art-787669d3df2c4b9d8e57640e1cb235f0
institution Directory Open Access Journal
issn 2075-163X
language English
last_indexed 2024-03-09T00:47:42Z
publishDate 2021-02-01
publisher MDPI AG
record_format Article
series Minerals
spelling doaj.art-787669d3df2c4b9d8e57640e1cb235f02023-12-11T17:24:16ZengMDPI AGMinerals2075-163X2021-02-0111221110.3390/min11020211Stepwise Utilization Process to Recover Valuable Components from Copper SlagSiwei Li0Zhengqi Guo1Jian Pan2Deqing Zhu3Tao Dong4Shenghu Lu5School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaWaste copper slag is a typical hazardous solid waste containing a variety of valuable elements and has not been effectively disposed of so far. In this paper, a stepwise extraction process was proposed to recover valuable elements (copper, iron, lead and zinc) from waste copper slag. The specific procedures are as follows: (1) A flotation process was adopted to enrich copper, and when the copper grade in the flotation concentrate was 21.50%, the copper recovery rate was 77.78%. (2) The flotation tailings were pelletized with limestone, then the green pellets were reduced, and the magnetic separation process was carried out. When the iron and copper grades in the magnetic concentrate were 90.21% Fe and 0.4% Cu, 91.34% iron and 83.41% copper were recovered, respectively. (3) Non-magnetic tailings were mixed with clinker and standard sand to produce common Portland cement. Several products were obtained from the waste copper slag through the proposed process: flotation concentrate, measured 21.50% Cu; magnetic concentrate, containing 90.21% TFe and 0.4% Cu; direct reduction dust, including 65.17% ZnO and 2.66% PbO; common Portland cement for building construction. The comprehensive utilization method for waste copper slag achieved zero tailing and has great potential for practical application.https://www.mdpi.com/2075-163X/11/2/211waste copper slagflotationdirect reduction-magnetic separationcommon Portland cement
spellingShingle Siwei Li
Zhengqi Guo
Jian Pan
Deqing Zhu
Tao Dong
Shenghu Lu
Stepwise Utilization Process to Recover Valuable Components from Copper Slag
Minerals
waste copper slag
flotation
direct reduction-magnetic separation
common Portland cement
title Stepwise Utilization Process to Recover Valuable Components from Copper Slag
title_full Stepwise Utilization Process to Recover Valuable Components from Copper Slag
title_fullStr Stepwise Utilization Process to Recover Valuable Components from Copper Slag
title_full_unstemmed Stepwise Utilization Process to Recover Valuable Components from Copper Slag
title_short Stepwise Utilization Process to Recover Valuable Components from Copper Slag
title_sort stepwise utilization process to recover valuable components from copper slag
topic waste copper slag
flotation
direct reduction-magnetic separation
common Portland cement
url https://www.mdpi.com/2075-163X/11/2/211
work_keys_str_mv AT siweili stepwiseutilizationprocesstorecovervaluablecomponentsfromcopperslag
AT zhengqiguo stepwiseutilizationprocesstorecovervaluablecomponentsfromcopperslag
AT jianpan stepwiseutilizationprocesstorecovervaluablecomponentsfromcopperslag
AT deqingzhu stepwiseutilizationprocesstorecovervaluablecomponentsfromcopperslag
AT taodong stepwiseutilizationprocesstorecovervaluablecomponentsfromcopperslag
AT shenghulu stepwiseutilizationprocesstorecovervaluablecomponentsfromcopperslag