Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate
In the title compound, C17H17N3O3S, the cyclopentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thiazolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phenyl ring....
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015017454 |
| _version_ | 1818960312033869824 |
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| author | Mehmet Akkurt Victoria A. Smolenski Shaaban K. Mohamed Jerry P. Jasinski Alaa A. Hassan Mustafa R. Albayati |
| author_facet | Mehmet Akkurt Victoria A. Smolenski Shaaban K. Mohamed Jerry P. Jasinski Alaa A. Hassan Mustafa R. Albayati |
| author_sort | Mehmet Akkurt |
| collection | DOAJ |
| description | In the title compound, C17H17N3O3S, the cyclopentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thiazolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phenyl ring. The molecular packing is stabilized by C—H...O and C—H...π interactions, forming a three-dimensional structure. |
| first_indexed | 2024-12-20T11:55:32Z |
| format | Article |
| id | doaj.art-789401afca6548d89c53630d55a0e884 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T11:55:32Z |
| publishDate | 2015-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-789401afca6548d89c53630d55a0e8842022-12-21T19:41:41ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-10-017110o776o77710.1107/S2056989015017454tk5388Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoateMehmet Akkurt0Victoria A. Smolenski1Shaaban K. Mohamed2Jerry P. Jasinski3Alaa A. Hassan4Mustafa R. Albayati5Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TurkeyDepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USAChemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, EnglandDepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USAChemistry Department, Faculty of Science, Minia University, 61519 El-Minia, EgyptKirkuk University, College of Science, Department of Chemistry, Kirkuk, IraqIn the title compound, C17H17N3O3S, the cyclopentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thiazolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phenyl ring. The molecular packing is stabilized by C—H...O and C—H...π interactions, forming a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S2056989015017454crystal structurethiazolidinyl ringdisorderhydrogen bondingC—H...π interactions |
| spellingShingle | Mehmet Akkurt Victoria A. Smolenski Shaaban K. Mohamed Jerry P. Jasinski Alaa A. Hassan Mustafa R. Albayati Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate Acta Crystallographica Section E: Crystallographic Communications crystal structure thiazolidinyl ring disorder hydrogen bonding C—H...π interactions |
| title | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_full | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_fullStr | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_full_unstemmed | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_short | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_sort | crystal structure of methyl 2z 2 2z 2 2 cyclopentylidenehydrazin 1 ylidene 4 oxo 3 phenyl 1 3 thiazolidin 5 ylidene ethanoate |
| topic | crystal structure thiazolidinyl ring disorder hydrogen bonding C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015017454 |
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