(Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)

The C2P2 donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94 (16)° and a P—Pt—P bond angle o...

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Main Authors: D. Paul Rillema, Curtis Moore, Ali Jehan
Format: Article
Language:English
Published: International Union of Crystallography 2016-08-01
Series:IUCrData
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616012773
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author D. Paul Rillema
Curtis Moore
Ali Jehan
author_facet D. Paul Rillema
Curtis Moore
Ali Jehan
author_sort D. Paul Rillema
collection DOAJ
description The C2P2 donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94 (16)° and a P—Pt—P bond angle of 93.40 (4)°. The average Pt—C bond length is 2.083 (3) Å [range 2.081 (4)–2.085 (4) Å]; the average Pt—P bond length is 2.308 (8) Å [range 2.3030 (11)–2.3136 (11) Å].
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spelling doaj.art-78ab4ae448e34fa688be8c3bbfa2359b2022-12-21T18:50:06ZengInternational Union of CrystallographyIUCrData2414-31462016-08-0118x16127710.1107/S2414314616012773wm4022(Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)D. Paul Rillema0Curtis Moore1Ali Jehan2Department of Chemistry, Wichita State University, Wichita, KS 67260, USACrystallographic Laboratory, University of California, San Diego, LaJolla, CA 92093, USADepartment of Chemistry, Wichita State University, Wichita, KS 67260, USAThe C2P2 donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94 (16)° and a P—Pt—P bond angle of 93.40 (4)°. The average Pt—C bond length is 2.083 (3) Å [range 2.081 (4)–2.085 (4) Å]; the average Pt—P bond length is 2.308 (8) Å [range 2.3030 (11)–2.3136 (11) Å].http://scripts.iucr.org/cgi-bin/paper?S2414314616012773crystal structureplatinum(II) biphenyl bis(diphenylphosphanyl)propane complex
spellingShingle D. Paul Rillema
Curtis Moore
Ali Jehan
(Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
IUCrData
crystal structure
platinum(II) biphenyl bis(diphenylphosphanyl)propane complex
title (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
title_full (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
title_fullStr (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
title_full_unstemmed (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
title_short (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
title_sort biphenyl 2 2 diyl 1 3 bis diphenylphosphanyl propane κ2p p platinum ii
topic crystal structure
platinum(II) biphenyl bis(diphenylphosphanyl)propane complex
url http://scripts.iucr.org/cgi-bin/paper?S2414314616012773
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AT curtismoore biphenyl22diyl13bisdiphenylphosphanylpropanek2ppplatinumii
AT alijehan biphenyl22diyl13bisdiphenylphosphanylpropanek2ppplatinumii