(Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)
The C2P2 donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94 (16)° and a P—Pt—P bond angle o...
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International Union of Crystallography
2016-08-01
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Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616012773 |
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author | D. Paul Rillema Curtis Moore Ali Jehan |
author_facet | D. Paul Rillema Curtis Moore Ali Jehan |
author_sort | D. Paul Rillema |
collection | DOAJ |
description | The C2P2 donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94 (16)° and a P—Pt—P bond angle of 93.40 (4)°. The average Pt—C bond length is 2.083 (3) Å [range 2.081 (4)–2.085 (4) Å]; the average Pt—P bond length is 2.308 (8) Å [range 2.3030 (11)–2.3136 (11) Å]. |
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format | Article |
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issn | 2414-3146 |
language | English |
last_indexed | 2024-12-21T21:12:39Z |
publishDate | 2016-08-01 |
publisher | International Union of Crystallography |
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spelling | doaj.art-78ab4ae448e34fa688be8c3bbfa2359b2022-12-21T18:50:06ZengInternational Union of CrystallographyIUCrData2414-31462016-08-0118x16127710.1107/S2414314616012773wm4022(Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II)D. Paul Rillema0Curtis Moore1Ali Jehan2Department of Chemistry, Wichita State University, Wichita, KS 67260, USACrystallographic Laboratory, University of California, San Diego, LaJolla, CA 92093, USADepartment of Chemistry, Wichita State University, Wichita, KS 67260, USAThe C2P2 donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94 (16)° and a P—Pt—P bond angle of 93.40 (4)°. The average Pt—C bond length is 2.083 (3) Å [range 2.081 (4)–2.085 (4) Å]; the average Pt—P bond length is 2.308 (8) Å [range 2.3030 (11)–2.3136 (11) Å].http://scripts.iucr.org/cgi-bin/paper?S2414314616012773crystal structureplatinum(II) biphenyl bis(diphenylphosphanyl)propane complex |
spellingShingle | D. Paul Rillema Curtis Moore Ali Jehan (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II) IUCrData crystal structure platinum(II) biphenyl bis(diphenylphosphanyl)propane complex |
title | (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II) |
title_full | (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II) |
title_fullStr | (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II) |
title_full_unstemmed | (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II) |
title_short | (Biphenyl-2,2′-diyl)[1,3-bis(diphenylphosphanyl)propane-κ2P,P′]platinum(II) |
title_sort | biphenyl 2 2 diyl 1 3 bis diphenylphosphanyl propane κ2p p platinum ii |
topic | crystal structure platinum(II) biphenyl bis(diphenylphosphanyl)propane complex |
url | http://scripts.iucr.org/cgi-bin/paper?S2414314616012773 |
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