Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching

<p>Abstract</p> <p>Films of nanocrystalline silicon (nc-Si) were prepared from hydrogenated amorphous silicon (a-Si:H) by using rapid thermal annealing. The formed nc-Si films were subjected to stain etching in hydrofluoric acid solutions in order to passivate surfaces of nc-Si. Th...

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Main Authors: Nikulin Valery, Mussabek Gaukhar, Taurbaev Yerzhan, Svanbayev Eldos, Taurbaev Toktar, Timoshenko Victor, Gonchar Kirill, Mirgorodskiy Ivan, Maslova Natalia
Format: Article
Language:English
Published: SpringerOpen 2011-01-01
Series:Nanoscale Research Letters
Online Access:http://www.nanoscalereslett.com/content/6/1/349
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author Nikulin Valery
Mussabek Gaukhar
Taurbaev Yerzhan
Svanbayev Eldos
Taurbaev Toktar
Timoshenko Victor
Gonchar Kirill
Mirgorodskiy Ivan
Maslova Natalia
author_facet Nikulin Valery
Mussabek Gaukhar
Taurbaev Yerzhan
Svanbayev Eldos
Taurbaev Toktar
Timoshenko Victor
Gonchar Kirill
Mirgorodskiy Ivan
Maslova Natalia
author_sort Nikulin Valery
collection DOAJ
description <p>Abstract</p> <p>Films of nanocrystalline silicon (nc-Si) were prepared from hydrogenated amorphous silicon (a-Si:H) by using rapid thermal annealing. The formed nc-Si films were subjected to stain etching in hydrofluoric acid solutions in order to passivate surfaces of nc-Si. The optical reflectance spectroscopy revealed the nc-Si formation as well as the high optical quality of the formed films. The Raman scattering spectroscopy was used to estimate the mean size and volume fraction of nc-Si in the annealed films, which were about 4 to 8 nm and 44 to 90%, respectively, depending on the annealing regime. In contrast to as-deposited a-Si:H films, the nc-Si films after stain etching exhibited efficient photoluminescence in the spectral range of 600 to 950 nm at room temperature. The photoluminescence intensity and lifetimes of the stain etched nc-Si films were similar to those for conventional porous Si formed by electrochemical etching. The obtained results indicate new possibilities to prepare luminescent thin films for Si-based optoelectronics.</p>
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spelling doaj.art-78e7c87518f047b795db8892c99c459a2023-09-02T16:10:52ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2011-01-0161349Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etchingNikulin ValeryMussabek GaukharTaurbaev YerzhanSvanbayev EldosTaurbaev ToktarTimoshenko VictorGonchar KirillMirgorodskiy IvanMaslova Natalia<p>Abstract</p> <p>Films of nanocrystalline silicon (nc-Si) were prepared from hydrogenated amorphous silicon (a-Si:H) by using rapid thermal annealing. The formed nc-Si films were subjected to stain etching in hydrofluoric acid solutions in order to passivate surfaces of nc-Si. The optical reflectance spectroscopy revealed the nc-Si formation as well as the high optical quality of the formed films. The Raman scattering spectroscopy was used to estimate the mean size and volume fraction of nc-Si in the annealed films, which were about 4 to 8 nm and 44 to 90%, respectively, depending on the annealing regime. In contrast to as-deposited a-Si:H films, the nc-Si films after stain etching exhibited efficient photoluminescence in the spectral range of 600 to 950 nm at room temperature. The photoluminescence intensity and lifetimes of the stain etched nc-Si films were similar to those for conventional porous Si formed by electrochemical etching. The obtained results indicate new possibilities to prepare luminescent thin films for Si-based optoelectronics.</p>http://www.nanoscalereslett.com/content/6/1/349
spellingShingle Nikulin Valery
Mussabek Gaukhar
Taurbaev Yerzhan
Svanbayev Eldos
Taurbaev Toktar
Timoshenko Victor
Gonchar Kirill
Mirgorodskiy Ivan
Maslova Natalia
Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
Nanoscale Research Letters
title Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
title_full Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
title_fullStr Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
title_full_unstemmed Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
title_short Efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
title_sort efficient visible luminescence of nanocrystalline silicon prepared from amorphous silicon films by thermal annealing and stain etching
url http://www.nanoscalereslett.com/content/6/1/349
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