Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain
A series of polyamide (PA)/montmorillonite nanocomposites containing pyrazine moiety in the main chain were synthesized by a convenient solution intercalation technique. PA 3 as a source of polymer matrix was synthesized by the direct polycondensation reaction of pyrazine-2,3-dicarboxylic acid 1 wit...
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| Format: | Article |
| Language: | English |
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De Gruyter
2012-09-01
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| Series: | Science and Engineering of Composite Materials |
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| Online Access: | https://doi.org/10.1515/secm-2011-0105 |
| _version_ | 1818609301603745792 |
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| author | Faghihi Khalil Naderi-Ghomi Mohammad Hajibeygi Mohsen |
| author_facet | Faghihi Khalil Naderi-Ghomi Mohammad Hajibeygi Mohsen |
| author_sort | Faghihi Khalil |
| collection | DOAJ |
| description | A series of polyamide (PA)/montmorillonite nanocomposites containing pyrazine moiety in the main chain were synthesized by a convenient solution intercalation technique. PA 3 as a source of polymer matrix was synthesized by the direct polycondensation reaction of pyrazine-2,3-dicarboxylic acid 1 with 4,4′-diaminodiphenyl sulfone 2 in the presence of triphenyl phosphite, CaCl2, pyridine, and N-methyl-2-pyrrolidone. The resulting nanocomposite films were characterized by Fourier transform infrared spectra, X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis (TGA). The results showed that organo-modified clay was dispersed homogeneously in the PA matrix. TGA indicated an enhancement of thermal stability of new nanocomposites compared with the pure polymer. |
| first_indexed | 2024-12-16T14:56:22Z |
| format | Article |
| id | doaj.art-78f741181a5d44adb362c2c5362b2bc9 |
| institution | Directory Open Access Journal |
| issn | 0792-1233 2191-0359 |
| language | English |
| last_indexed | 2024-12-16T14:56:22Z |
| publishDate | 2012-09-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Science and Engineering of Composite Materials |
| spelling | doaj.art-78f741181a5d44adb362c2c5362b2bc92022-12-21T22:27:26ZengDe GruyterScience and Engineering of Composite Materials0792-12332191-03592012-09-0119321522010.1515/secm-2011-0105Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chainFaghihi Khalil0Naderi-Ghomi Mohammad1Hajibeygi Mohsen2Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, IranDepartment of Chemistry, Arak Branch, Islamic Azad University, Arak, IranDepartment of Chemistry, Varamin Pishva Branch, Islamic Azad University, Varamin, IranA series of polyamide (PA)/montmorillonite nanocomposites containing pyrazine moiety in the main chain were synthesized by a convenient solution intercalation technique. PA 3 as a source of polymer matrix was synthesized by the direct polycondensation reaction of pyrazine-2,3-dicarboxylic acid 1 with 4,4′-diaminodiphenyl sulfone 2 in the presence of triphenyl phosphite, CaCl2, pyridine, and N-methyl-2-pyrrolidone. The resulting nanocomposite films were characterized by Fourier transform infrared spectra, X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis (TGA). The results showed that organo-modified clay was dispersed homogeneously in the PA matrix. TGA indicated an enhancement of thermal stability of new nanocomposites compared with the pure polymer.https://doi.org/10.1515/secm-2011-0105nanocompositepolyamidepyrazinethermal stable |
| spellingShingle | Faghihi Khalil Naderi-Ghomi Mohammad Hajibeygi Mohsen Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain Science and Engineering of Composite Materials nanocomposite polyamide pyrazine thermal stable |
| title | Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain |
| title_full | Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain |
| title_fullStr | Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain |
| title_full_unstemmed | Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain |
| title_short | Synthesis and properties of new polyamide-organoclay nanocomposites containing pyrazine moiety in the main chain |
| title_sort | synthesis and properties of new polyamide organoclay nanocomposites containing pyrazine moiety in the main chain |
| topic | nanocomposite polyamide pyrazine thermal stable |
| url | https://doi.org/10.1515/secm-2011-0105 |
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