The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films

Cellulose nanocrystal  )CNC) is a type of nanomaterial which is produced by  partial hydrolysis of cellulose and elimination of its amorphous regions. CNC has several advantages such as biodegradability and safety toward human health. In this study, CNC was produced from cotton linters and methods s...

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Main Authors: Leila Abolghasemi Fakhri, Babak Ghanbarzadeh, Jalal Dehghannia, Ali Akbar Entezami
Format: Article
Language:fas
Published: Iran Polymer and Petrochemical Institute 2013-01-01
Series:علوم و تکنولوژی پلیمر
Subjects:
Online Access:http://jips.ippi.ac.ir/article_610_21d6aaa014bdc9892f6a14c2e1c1c306.pdf
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author Leila Abolghasemi Fakhri
Babak Ghanbarzadeh
Jalal Dehghannia
Ali Akbar Entezami
author_facet Leila Abolghasemi Fakhri
Babak Ghanbarzadeh
Jalal Dehghannia
Ali Akbar Entezami
author_sort Leila Abolghasemi Fakhri
collection DOAJ
description Cellulose nanocrystal  )CNC) is a type of nanomaterial which is produced by  partial hydrolysis of cellulose and elimination of its amorphous regions. CNC has several advantages such as biodegradability and safety toward human health. In this study, CNC was produced from cotton linters and methods such as transmission electron microscopy and atomic force microscopy were used for confrmation of nanoscale  size production of cellulose crystals. Carboxymethyl cellulose  )CMC)/polyvinyl alcohol  )PVA)-nanoclay  )MMT) and CMC-PVA-CNC flms, containing 3-10% (wt/wt CMC) nanofllers, were prepared by casting method and their physical properties were compared in order to approve the use of CNC instead of MMT for its contribution in improving the physical properties of carboxymethyl cellulose-based  flms.  The  X-ray  diffraction  results  indicated  the  formation  of  an exfoliated nanostructure at all nanoparticle concentrations. The results showed that there was no signifcant difference (p < 0.5) between the moisture absorption properties of flms containing the two types of nanofller. The flms containing nanoclay showed higher mechanical strength compared to those containing CNC. The ultimate tensile strengths of the flms containing 10% nanoclay and CNC were higher than the control flm (69.72% and 47.05%, respectively).
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spelling doaj.art-78fcb082b1624e04a12481760f3c3a2d2022-12-21T23:09:35ZfasIran Polymer and Petrochemical Instituteعلوم و تکنولوژی پلیمر1016-32552008-08832013-01-0124645546610.22063/jipst.2013.610610The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend FilmsLeila Abolghasemi FakhriBabak GhanbarzadehJalal DehghanniaAli Akbar EntezamiCellulose nanocrystal  )CNC) is a type of nanomaterial which is produced by  partial hydrolysis of cellulose and elimination of its amorphous regions. CNC has several advantages such as biodegradability and safety toward human health. In this study, CNC was produced from cotton linters and methods such as transmission electron microscopy and atomic force microscopy were used for confrmation of nanoscale  size production of cellulose crystals. Carboxymethyl cellulose  )CMC)/polyvinyl alcohol  )PVA)-nanoclay  )MMT) and CMC-PVA-CNC flms, containing 3-10% (wt/wt CMC) nanofllers, were prepared by casting method and their physical properties were compared in order to approve the use of CNC instead of MMT for its contribution in improving the physical properties of carboxymethyl cellulose-based  flms.  The  X-ray  diffraction  results  indicated  the  formation  of  an exfoliated nanostructure at all nanoparticle concentrations. The results showed that there was no signifcant difference (p < 0.5) between the moisture absorption properties of flms containing the two types of nanofller. The flms containing nanoclay showed higher mechanical strength compared to those containing CNC. The ultimate tensile strengths of the flms containing 10% nanoclay and CNC were higher than the control flm (69.72% and 47.05%, respectively).http://jips.ippi.ac.ir/article_610_21d6aaa014bdc9892f6a14c2e1c1c306.pdfmoisture absorptionmechanical propertiescolor propertiesnanoclaycellulose nanocrystal
spellingShingle Leila Abolghasemi Fakhri
Babak Ghanbarzadeh
Jalal Dehghannia
Ali Akbar Entezami
The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films
علوم و تکنولوژی پلیمر
moisture absorption
mechanical properties
color properties
nanoclay
cellulose nanocrystal
title The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films
title_full The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films
title_fullStr The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films
title_full_unstemmed The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films
title_short The Effects of Montmorillonite and Cellulose Nanocrystals on Physical Properties of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Films
title_sort effects of montmorillonite and cellulose nanocrystals on physical properties of carboxymethyl cellulose polyvinyl alcohol blend films
topic moisture absorption
mechanical properties
color properties
nanoclay
cellulose nanocrystal
url http://jips.ippi.ac.ir/article_610_21d6aaa014bdc9892f6a14c2e1c1c306.pdf
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