Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries
Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an except...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2017-04-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-017-01086-8 |
| _version_ | 1818425344927989760 |
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| author | Changling Li Chueh Liu Wei Wang Zafer Mutlu Jeffrey Bell Kazi Ahmed Rachel Ye Mihrimah Ozkan Cengiz S. Ozkan |
| author_facet | Changling Li Chueh Liu Wei Wang Zafer Mutlu Jeffrey Bell Kazi Ahmed Rachel Ye Mihrimah Ozkan Cengiz S. Ozkan |
| author_sort | Changling Li |
| collection | DOAJ |
| description | Abstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density. |
| first_indexed | 2024-12-14T14:12:27Z |
| format | Article |
| id | doaj.art-7904b93fc2f74848b6d7c8135f538a6b |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-12-14T14:12:27Z |
| publishDate | 2017-04-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-7904b93fc2f74848b6d7c8135f538a6b2022-12-21T22:58:16ZengNature PortfolioScientific Reports2045-23222017-04-017111110.1038/s41598-017-01086-8Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell BatteriesChangling Li0Chueh Liu1Wei Wang2Zafer Mutlu3Jeffrey Bell4Kazi Ahmed5Rachel Ye6Mihrimah Ozkan7Cengiz S. Ozkan8Materials Science and Engineering Program, Department of Mechanical Engineering, University of CaliforniaDepartment of Electrical and Computer Engineering, Department of Chemistry, University of CaliforniaMaterials Science and Engineering Program, Department of Mechanical Engineering, University of CaliforniaMaterials Science and Engineering Program, Department of Mechanical Engineering, University of CaliforniaMaterials Science and Engineering Program, Department of Mechanical Engineering, University of CaliforniaMaterials Science and Engineering Program, Department of Mechanical Engineering, University of CaliforniaDepartment of Electrical and Computer Engineering, Department of Chemistry, University of CaliforniaDepartment of Electrical and Computer Engineering, Department of Chemistry, University of CaliforniaMaterials Science and Engineering Program, Department of Mechanical Engineering, University of CaliforniaAbstract Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g−1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g−1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density.https://doi.org/10.1038/s41598-017-01086-8 |
| spellingShingle | Changling Li Chueh Liu Wei Wang Zafer Mutlu Jeffrey Bell Kazi Ahmed Rachel Ye Mihrimah Ozkan Cengiz S. Ozkan Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries Scientific Reports |
| title | Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
| title_full | Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
| title_fullStr | Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
| title_full_unstemmed | Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
| title_short | Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries |
| title_sort | silicon derived from glass bottles as anode materials for lithium ion full cell batteries |
| url | https://doi.org/10.1038/s41598-017-01086-8 |
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