Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell

We develop a semi-analytical model for polarization curve of a polymer electrolyte membrane (PEM) fuel cell with distributed (aged) along the oxygen channel MEA transport and kinetic parameters of the membrane–electrode assembly (MEA). We show that the curve corresponding to varying along the channe...

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Main Author: Andrei Kulikovsky
Format: Article
Language:English
Published: MDPI AG 2014-01-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/7/1/351
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author Andrei Kulikovsky
author_facet Andrei Kulikovsky
author_sort Andrei Kulikovsky
collection DOAJ
description We develop a semi-analytical model for polarization curve of a polymer electrolyte membrane (PEM) fuel cell with distributed (aged) along the oxygen channel MEA transport and kinetic parameters of the membrane–electrode assembly (MEA). We show that the curve corresponding to varying along the channel parameter, in general, does not reduce to the curve for a certain constant value of this parameter. A possibility to determine the shape of the deteriorated MEA parameter along the oxygen channel by fitting the model equation to the cell polarization data is demonstrated.
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spelling doaj.art-790c1f24dc804a08a33d4dbb4b8fdafc2022-12-22T04:19:53ZengMDPI AGEnergies1996-10732014-01-017135136410.3390/en7010351en7010351Polarization Curve of a Non-Uniformly Aged PEM Fuel CellAndrei Kulikovsky0Institute of Energy and Climate Research—Electrochemical Process Engineering (IEK-3), Research Center "Juelich", Juelich D-52425, GermanyWe develop a semi-analytical model for polarization curve of a polymer electrolyte membrane (PEM) fuel cell with distributed (aged) along the oxygen channel MEA transport and kinetic parameters of the membrane–electrode assembly (MEA). We show that the curve corresponding to varying along the channel parameter, in general, does not reduce to the curve for a certain constant value of this parameter. A possibility to determine the shape of the deteriorated MEA parameter along the oxygen channel by fitting the model equation to the cell polarization data is demonstrated.http://www.mdpi.com/1996-1073/7/1/351PEMFCagingmodeling
spellingShingle Andrei Kulikovsky
Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell
Energies
PEMFC
aging
modeling
title Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell
title_full Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell
title_fullStr Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell
title_full_unstemmed Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell
title_short Polarization Curve of a Non-Uniformly Aged PEM Fuel Cell
title_sort polarization curve of a non uniformly aged pem fuel cell
topic PEMFC
aging
modeling
url http://www.mdpi.com/1996-1073/7/1/351
work_keys_str_mv AT andreikulikovsky polarizationcurveofanonuniformlyagedpemfuelcell