Observation of site-selective chemical bond changes via ultrafast chemical shifts
X-ray photoelectron spectroscopy probes the chemical environment in a molecule at a specific atomic site. Here the authors extend this concept with a site selective trigger to follow chemical bond changes as they occur on the femtosecond time scale.
| Main Authors: | , , , , , , , , , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-11-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-34670-2 |
| _version_ | 1811186884567629824 |
|---|---|
| author | Andre Al-Haddad Solène Oberli Jesús González-Vázquez Maximilian Bucher Gilles Doumy Phay Ho Jacek Krzywinski Thomas J. Lane Alberto Lutman Agostino Marinelli Timothy J. Maxwell Stefan Moeller Stephen T. Pratt Dipanwita Ray Ron Shepard Stephen H. Southworth Álvaro Vázquez-Mayagoitia Peter Walter Linda Young Antonio Picón Christoph Bostedt |
| author_facet | Andre Al-Haddad Solène Oberli Jesús González-Vázquez Maximilian Bucher Gilles Doumy Phay Ho Jacek Krzywinski Thomas J. Lane Alberto Lutman Agostino Marinelli Timothy J. Maxwell Stefan Moeller Stephen T. Pratt Dipanwita Ray Ron Shepard Stephen H. Southworth Álvaro Vázquez-Mayagoitia Peter Walter Linda Young Antonio Picón Christoph Bostedt |
| author_sort | Andre Al-Haddad |
| collection | DOAJ |
| description | X-ray photoelectron spectroscopy probes the chemical environment in a molecule at a specific atomic site. Here the authors extend this concept with a site selective trigger to follow chemical bond changes as they occur on the femtosecond time scale. |
| first_indexed | 2024-04-11T13:53:46Z |
| format | Article |
| id | doaj.art-790ca6a546db4a61a506d320dcb718c9 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-11T13:53:46Z |
| publishDate | 2022-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-790ca6a546db4a61a506d320dcb718c92022-12-22T04:20:27ZengNature PortfolioNature Communications2041-17232022-11-011311710.1038/s41467-022-34670-2Observation of site-selective chemical bond changes via ultrafast chemical shiftsAndre Al-Haddad0Solène Oberli1Jesús González-Vázquez2Maximilian Bucher3Gilles Doumy4Phay Ho5Jacek Krzywinski6Thomas J. Lane7Alberto Lutman8Agostino Marinelli9Timothy J. Maxwell10Stefan Moeller11Stephen T. Pratt12Dipanwita Ray13Ron Shepard14Stephen H. Southworth15Álvaro Vázquez-Mayagoitia16Peter Walter17Linda Young18Antonio Picón19Christoph Bostedt20Chemical Sciences and Engineering Division, Argonne National LaboratoryDepartamento de Química, Universidad Autónoma de MadridDepartamento de Química, Universidad Autónoma de MadridChemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratorySLAC National Accelerator LaboratorySLAC National Accelerator LaboratorySLAC National Accelerator LaboratorySLAC National Accelerator LaboratorySLAC National Accelerator LaboratorySLAC National Accelerator LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratorySLAC National Accelerator LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryArgonne Leadership Computing FacilitySLAC National Accelerator LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryX-ray photoelectron spectroscopy probes the chemical environment in a molecule at a specific atomic site. Here the authors extend this concept with a site selective trigger to follow chemical bond changes as they occur on the femtosecond time scale.https://doi.org/10.1038/s41467-022-34670-2 |
| spellingShingle | Andre Al-Haddad Solène Oberli Jesús González-Vázquez Maximilian Bucher Gilles Doumy Phay Ho Jacek Krzywinski Thomas J. Lane Alberto Lutman Agostino Marinelli Timothy J. Maxwell Stefan Moeller Stephen T. Pratt Dipanwita Ray Ron Shepard Stephen H. Southworth Álvaro Vázquez-Mayagoitia Peter Walter Linda Young Antonio Picón Christoph Bostedt Observation of site-selective chemical bond changes via ultrafast chemical shifts Nature Communications |
| title | Observation of site-selective chemical bond changes via ultrafast chemical shifts |
| title_full | Observation of site-selective chemical bond changes via ultrafast chemical shifts |
| title_fullStr | Observation of site-selective chemical bond changes via ultrafast chemical shifts |
| title_full_unstemmed | Observation of site-selective chemical bond changes via ultrafast chemical shifts |
| title_short | Observation of site-selective chemical bond changes via ultrafast chemical shifts |
| title_sort | observation of site selective chemical bond changes via ultrafast chemical shifts |
| url | https://doi.org/10.1038/s41467-022-34670-2 |
| work_keys_str_mv | AT andrealhaddad observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT soleneoberli observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT jesusgonzalezvazquez observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT maximilianbucher observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT gillesdoumy observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT phayho observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT jacekkrzywinski observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT thomasjlane observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT albertolutman observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT agostinomarinelli observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT timothyjmaxwell observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT stefanmoeller observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT stephentpratt observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT dipanwitaray observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT ronshepard observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT stephenhsouthworth observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT alvarovazquezmayagoitia observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT peterwalter observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT lindayoung observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT antoniopicon observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts AT christophbostedt observationofsiteselectivechemicalbondchangesviaultrafastchemicalshifts |