Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy

The solid state phase transformation kinetics of as-cast and cold rolling deformed Al<sub>0.5</sub>CoCrFeNi high-entropy alloys have been investigated by the thermal expansion method. The phase transformed volume fractions are determined from the thermal expansion curve using the lever r...

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Main Authors: Jun Wang, Haoxue Yang, Tong Guo, Jiaxiang Wang, William Yi Wang, Jinshan Li
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/20/12/917
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author Jun Wang
Haoxue Yang
Tong Guo
Jiaxiang Wang
William Yi Wang
Jinshan Li
author_facet Jun Wang
Haoxue Yang
Tong Guo
Jiaxiang Wang
William Yi Wang
Jinshan Li
author_sort Jun Wang
collection DOAJ
description The solid state phase transformation kinetics of as-cast and cold rolling deformed Al<sub>0.5</sub>CoCrFeNi high-entropy alloys have been investigated by the thermal expansion method. The phase transformed volume fractions are determined from the thermal expansion curve using the lever rule method, and the deformed sample exhibits a much higher transformation rate. Two kinetic parameters, activation energy (<i>E</i>) and kinetic exponent (<i>n</i>) are determined using Kissinger&#8315; Akahira&#8315;Sunose (KAS) and Johnson&#8315;Mehl&#8315;Avrami (JMA) method, respectively. Results show that a pre-deformed sample shows a much lower activation energy and higher kinetic exponent compared with the as-cast sample, which are interpreted based on the deformation induced defects that can promote the nucleation and growth process during phase transformation.
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spelling doaj.art-7926788a03184c19be385b4ed6982fc82022-12-22T03:19:31ZengMDPI AGEntropy1099-43002018-11-01201291710.3390/e20120917e20120917Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy AlloyJun Wang0Haoxue Yang1Tong Guo2Jiaxiang Wang3William Yi Wang4Jinshan Li5State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, ChinaThe solid state phase transformation kinetics of as-cast and cold rolling deformed Al<sub>0.5</sub>CoCrFeNi high-entropy alloys have been investigated by the thermal expansion method. The phase transformed volume fractions are determined from the thermal expansion curve using the lever rule method, and the deformed sample exhibits a much higher transformation rate. Two kinetic parameters, activation energy (<i>E</i>) and kinetic exponent (<i>n</i>) are determined using Kissinger&#8315; Akahira&#8315;Sunose (KAS) and Johnson&#8315;Mehl&#8315;Avrami (JMA) method, respectively. Results show that a pre-deformed sample shows a much lower activation energy and higher kinetic exponent compared with the as-cast sample, which are interpreted based on the deformation induced defects that can promote the nucleation and growth process during phase transformation.https://www.mdpi.com/1099-4300/20/12/917high-entropy alloyphase transformationkineticsdeformationthermal expansion
spellingShingle Jun Wang
Haoxue Yang
Tong Guo
Jiaxiang Wang
William Yi Wang
Jinshan Li
Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy
Entropy
high-entropy alloy
phase transformation
kinetics
deformation
thermal expansion
title Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy
title_full Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy
title_fullStr Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy
title_full_unstemmed Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy
title_short Effect of Cold Rolling on the Phase Transformation Kinetics of an Al<sub>0.5</sub>CoCrFeNi High-Entropy Alloy
title_sort effect of cold rolling on the phase transformation kinetics of an al sub 0 5 sub cocrfeni high entropy alloy
topic high-entropy alloy
phase transformation
kinetics
deformation
thermal expansion
url https://www.mdpi.com/1099-4300/20/12/917
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