Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究)
制备了用于气相选择性氧化制对叔丁基苯甲醛的催化剂.通过反应温度、进料浓度、空速、催化剂寿命等条件的考察,讨论了影响反应的因素.结果表明,在合适的反应条件下产物对叔丁基苯甲醛选择性可达80 mol%以上,反应物对叔丁基甲苯转化率大于12 mol%,且催化剂经365 h长时间寿命试验活性仍较稳定,无论从工业应用前景角度来看,还是在环境保护方面都具有很大意义....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2002-05-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2002.29.3.304-307 |
| _version_ | 1797236487121534976 |
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| author | CHENMin(陈敏) YUANXian-xin(袁贤鑫) ZHOURen-xian(周仁贤) ZHENGXiao-ming(郑小明) |
| author_facet | CHENMin(陈敏) YUANXian-xin(袁贤鑫) ZHOURen-xian(周仁贤) ZHENGXiao-ming(郑小明) |
| author_sort | CHENMin(陈敏) |
| collection | DOAJ |
| description | 制备了用于气相选择性氧化制对叔丁基苯甲醛的催化剂.通过反应温度、进料浓度、空速、催化剂寿命等条件的考察,讨论了影响反应的因素.结果表明,在合适的反应条件下产物对叔丁基苯甲醛选择性可达80 mol%以上,反应物对叔丁基甲苯转化率大于12 mol%,且催化剂经365 h长时间寿命试验活性仍较稳定,无论从工业应用前景角度来看,还是在环境保护方面都具有很大意义. |
| first_indexed | 2024-04-24T17:04:38Z |
| format | Article |
| id | doaj.art-79462d5b21ee4baaa0b2bc80facaf905 |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:04:38Z |
| publishDate | 2002-05-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-79462d5b21ee4baaa0b2bc80facaf9052024-03-29T01:58:18ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972002-05-01293304307zjup/1008-9497.2002.29.3.304-307Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究)CHENMin(陈敏)0YUANXian-xin(袁贤鑫)1ZHOURen-xian(周仁贤)2ZHENGXiao-ming(郑小明)3Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系，浙江 杭州 310028)Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系，浙江 杭州 310028)Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系，浙江 杭州 310028)Department of Chemistry, Zhejiang University, Hangzhou 310028, China(浙江大学化学系，浙江 杭州 310028)制备了用于气相选择性氧化制对叔丁基苯甲醛的催化剂.通过反应温度、进料浓度、空速、催化剂寿命等条件的考察,讨论了影响反应的因素.结果表明,在合适的反应条件下产物对叔丁基苯甲醛选择性可达80 mol%以上,反应物对叔丁基甲苯转化率大于12 mol%,且催化剂经365 h长时间寿命试验活性仍较稳定,无论从工业应用前景角度来看,还是在环境保护方面都具有很大意义.https://doi.org/zjup/1008-9497.2002.29.3.304-307选择氧化对叔丁基苯甲醛催化剂 |
| spellingShingle | CHENMin(陈敏) YUANXian-xin(袁贤鑫) ZHOURen-xian(周仁贤) ZHENGXiao-ming(郑小明) Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究) Zhejiang Daxue xuebao. Lixue ban 选择氧化 对叔丁基苯甲醛 催化剂 |
| title | Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究) |
| title_full | Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究) |
| title_fullStr | Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究) |
| title_full_unstemmed | Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究) |
| title_short | Study of the catalyst for the vapor phase selective oxidation from p-tert butyl toluene to p-tert benzalde-hyde(选择氧化制对叔丁基苯甲醛催化剂研究) |
| title_sort | study of the catalyst for the vapor phase selective oxidation from p tert butyl toluene to p tert benzalde hyde 选择氧化制对叔丁基苯甲醛催化剂研究 |
| topic | 选择氧化 对叔丁基苯甲醛 催化剂 |
| url | https://doi.org/zjup/1008-9497.2002.29.3.304-307 |
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