Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)]
The dinuclear centrosymmetric title compound, [Cu2(CH3CO2)4(C5H8N2)2], has a distorted square-pyramidal coordination geometry around each CuII atom in which four O atoms from the bridging acetate ligands form the basal plane while two N atoms from the pyrazole ligands occupy the apical positions. Th...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811032600 |
| _version_ | 1819290444026085376 |
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| author | Juanita van Wyk Bernard Omondi James Darkwa |
| author_facet | Juanita van Wyk Bernard Omondi James Darkwa |
| author_sort | Juanita van Wyk |
| collection | DOAJ |
| description | The dinuclear centrosymmetric title compound, [Cu2(CH3CO2)4(C5H8N2)2], has a distorted square-pyramidal coordination geometry around each CuII atom in which four O atoms from the bridging acetate ligands form the basal plane while two N atoms from the pyrazole ligands occupy the apical positions. The crystal has two half molecules in the asymmetric unit with a Cu...Cu distance of 2.6762 (4) Å. Disorder was found for two O atoms and two C atoms of one acetate ligand and refined with occupancies of 0.265 (7) and 0.735 (7). The crystal also features molecules linked through two N—H...O hydrogen bonds resulting in one-dimensional chains extending along the crystallographic b axis. |
| first_indexed | 2024-12-24T03:22:50Z |
| format | Article |
| id | doaj.art-796c5f39ce1f476280d9761d5345d848 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:22:50Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-796c5f39ce1f476280d9761d5345d8482022-12-21T17:17:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1299m129910.1107/S1600536811032600Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)]Juanita van WykBernard OmondiJames DarkwaThe dinuclear centrosymmetric title compound, [Cu2(CH3CO2)4(C5H8N2)2], has a distorted square-pyramidal coordination geometry around each CuII atom in which four O atoms from the bridging acetate ligands form the basal plane while two N atoms from the pyrazole ligands occupy the apical positions. The crystal has two half molecules in the asymmetric unit with a Cu...Cu distance of 2.6762 (4) Å. Disorder was found for two O atoms and two C atoms of one acetate ligand and refined with occupancies of 0.265 (7) and 0.735 (7). The crystal also features molecules linked through two N—H...O hydrogen bonds resulting in one-dimensional chains extending along the crystallographic b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536811032600 |
| spellingShingle | Juanita van Wyk Bernard Omondi James Darkwa Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)] Acta Crystallographica Section E |
| title | Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)] |
| title_full | Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)] |
| title_fullStr | Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)] |
| title_full_unstemmed | Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)] |
| title_short | Tetra-μ-acetato-κ8O:O′-bis[(3,5-dimethyl-1H-pyrazole-κN2)copper(II)] |
| title_sort | tetra amp 956 acetato amp 954 8o o amp 8242 bis 3 5 dimethyl 1h pyrazole amp 954 n2 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811032600 |
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