Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T
Herein, we report a novel transparent engineering plastic nylon 10I/10T based on bio-based poly(decamethylene isophthalamide) (nylon10I). We have demonstrated the one-step melt polycondensation synthesis of transparent nylon and carried out Fourier transform infrared spectroscopy (FT-IR) and proton...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Taylor & Francis Group
2018-01-01
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| Series: | Designed Monomers and Polymers |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1080/15685551.2018.1543633 |
| _version_ | 1811193825170817024 |
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| author | Bingxiao Liu Guosheng Hu Jingting Zhang Chunhui Fang |
| author_facet | Bingxiao Liu Guosheng Hu Jingting Zhang Chunhui Fang |
| author_sort | Bingxiao Liu |
| collection | DOAJ |
| description | Herein, we report a novel transparent engineering plastic nylon 10I/10T based on bio-based poly(decamethylene isophthalamide) (nylon10I). We have demonstrated the one-step melt polycondensation synthesis of transparent nylon and carried out Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance (1H NMR) to confirm the chemical structure. Furthermore, the dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) were used to analyze the thermal properties. Glass transition temperature (Tg) and thermal decomposition onset temperature (T1) of nylon 10I/10T (15 wt. % 10T) were 118.9 and 438.0 °C, respectively. The intrinsic viscosity, water absorption, light transmittance, mechanical properties, solvent resistance and the decomposition mechanism of nylon 10I/10T have also been investigated. The results show that the nylon 10I/10T has lower water absorption and enhanced solvent resistance compared to nylon 6–3-T, which indicates that nylon 10I/10T is a promising transparent plastic. |
| first_indexed | 2024-04-12T00:15:55Z |
| format | Article |
| id | doaj.art-79713406f52c417496ec01c7c3d358e3 |
| institution | Directory Open Access Journal |
| issn | 1568-5551 |
| language | English |
| last_indexed | 2024-04-12T00:15:55Z |
| publishDate | 2018-01-01 |
| publisher | Taylor & Francis Group |
| record_format | Article |
| series | Designed Monomers and Polymers |
| spelling | doaj.art-79713406f52c417496ec01c7c3d358e32022-12-22T03:55:50ZengTaylor & Francis GroupDesigned Monomers and Polymers1568-55512018-01-0121118219210.1080/15685551.2018.15436331543633Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10TBingxiao Liu0Guosheng Hu1Jingting Zhang2Chunhui Fang3North University of ChinaNorth University of ChinaNorth University of ChinaNorth University of ChinaHerein, we report a novel transparent engineering plastic nylon 10I/10T based on bio-based poly(decamethylene isophthalamide) (nylon10I). We have demonstrated the one-step melt polycondensation synthesis of transparent nylon and carried out Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance (1H NMR) to confirm the chemical structure. Furthermore, the dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) were used to analyze the thermal properties. Glass transition temperature (Tg) and thermal decomposition onset temperature (T1) of nylon 10I/10T (15 wt. % 10T) were 118.9 and 438.0 °C, respectively. The intrinsic viscosity, water absorption, light transmittance, mechanical properties, solvent resistance and the decomposition mechanism of nylon 10I/10T have also been investigated. The results show that the nylon 10I/10T has lower water absorption and enhanced solvent resistance compared to nylon 6–3-T, which indicates that nylon 10I/10T is a promising transparent plastic.http://dx.doi.org/10.1080/15685551.2018.1543633Bio-basednylonmelt polymerizationthermal decomposition kineticsactivation energy (E) |
| spellingShingle | Bingxiao Liu Guosheng Hu Jingting Zhang Chunhui Fang Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T Designed Monomers and Polymers Bio-based nylon melt polymerization thermal decomposition kinetics activation energy (E) |
| title | Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T |
| title_full | Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T |
| title_fullStr | Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T |
| title_full_unstemmed | Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T |
| title_short | Synthesis, characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T |
| title_sort | synthesis characterization and thermal decomposition kinetics of a bio based transparent nylon 10i 10t |
| topic | Bio-based nylon melt polymerization thermal decomposition kinetics activation energy (E) |
| url | http://dx.doi.org/10.1080/15685551.2018.1543633 |
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