EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ)
For many years, the goal of transitioning from conventional to renewable fuels (bioethanol and biodiesel) has been encouraged by government entities. However, due to the hygroscopicity of ethanol, ethanol/biodiesel blends can accelerate corrosion in metallurgy. Therefore, inhibitors can be added to...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2024-01-01
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| Series: | Química Nova |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422024000100001&lng=en&tlng=en |
| _version_ | 1797361081456263168 |
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| author | Chaza Joumaa Ibtissam Saad Ghassan Younes |
| author_facet | Chaza Joumaa Ibtissam Saad Ghassan Younes |
| author_sort | Chaza Joumaa |
| collection | DOAJ |
| description | For many years, the goal of transitioning from conventional to renewable fuels (bioethanol and biodiesel) has been encouraged by government entities. However, due to the hygroscopicity of ethanol, ethanol/biodiesel blends can accelerate corrosion in metallurgy. Therefore, inhibitors can be added to mitigate corrosion. This research studied the effect of adding ethanol to diesel/biodiesel blends and measured the rate of corrosion on various metals (aluminum, copper, and 304 stainless steel) by the electrochemical impedance spectroscopy (EIS) method. The results indicated the corrosion rate increased with increasing the percentage of ethanol in the blends, and the corrosion inhibition efficiency of tert-butylhydroquinone (TBHQ) decreased upon the addition of ethanol. TBHQ was most effective as a corrosion inhibitor in the B15E5 blend. The inhibition efficiency of TBHQ decrease with the increase of the temperature. The adsorption process and the electrochemical parameters were calculated and discussed. |
| first_indexed | 2024-03-08T15:48:49Z |
| format | Article |
| id | doaj.art-7991e3eb83ae4a37a2e9d248c297bdd8 |
| institution | Directory Open Access Journal |
| issn | 1678-7064 |
| language | English |
| last_indexed | 2024-03-08T15:48:49Z |
| publishDate | 2024-01-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj.art-7991e3eb83ae4a37a2e9d248c297bdd82024-01-09T07:42:46ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642024-01-0147110.21577/0100-4042.20230083EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ)Chaza Joumaahttps://orcid.org/0000-0002-2884-1608Ibtissam SaadGhassan YounesFor many years, the goal of transitioning from conventional to renewable fuels (bioethanol and biodiesel) has been encouraged by government entities. However, due to the hygroscopicity of ethanol, ethanol/biodiesel blends can accelerate corrosion in metallurgy. Therefore, inhibitors can be added to mitigate corrosion. This research studied the effect of adding ethanol to diesel/biodiesel blends and measured the rate of corrosion on various metals (aluminum, copper, and 304 stainless steel) by the electrochemical impedance spectroscopy (EIS) method. The results indicated the corrosion rate increased with increasing the percentage of ethanol in the blends, and the corrosion inhibition efficiency of tert-butylhydroquinone (TBHQ) decreased upon the addition of ethanol. TBHQ was most effective as a corrosion inhibitor in the B15E5 blend. The inhibition efficiency of TBHQ decrease with the increase of the temperature. The adsorption process and the electrochemical parameters were calculated and discussed.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422024000100001&lng=en&tlng=enDBE blendcorrosionelectrochemical impedance spectroscopytert-butylhydroquinone |
| spellingShingle | Chaza Joumaa Ibtissam Saad Ghassan Younes EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ) Química Nova DBE blend corrosion electrochemical impedance spectroscopy tert-butylhydroquinone |
| title | EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ) |
| title_full | EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ) |
| title_fullStr | EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ) |
| title_full_unstemmed | EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ) |
| title_short | EFFECT OF DIESEL-BIODIESEL-ETHANOL MIXTURES ON CORROSION RATE OF VARIOUS METALS IN THE PRESENCE OF TERT-BUTYLHYDROQUINONE (TBHQ) |
| title_sort | effect of diesel biodiesel ethanol mixtures on corrosion rate of various metals in the presence of tert butylhydroquinone tbhq |
| topic | DBE blend corrosion electrochemical impedance spectroscopy tert-butylhydroquinone |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422024000100001&lng=en&tlng=en |
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