Tandem conversion xylose to 2-methylfuran with NiCu/C catalyst

Nowadays, 2-methylfuran is urgently needed especially in pharmaceutical manufacture. However, the direct synthesis of 2-methylfuran via the efficient dehydration and hydrogenation of xylose usually requires a multistep reaction. Herein, a route of tandem conversion xylose to 2-methylfuran was develo...

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Bibliographic Details
Main Authors: Hao Li, Huimin Liu, Chiliu Cai, Haiyong Wang, Youwang Huang, Song Li, Bin Yang, Chenguang Wang, Yuhe Liao, Longlong Ma
Format: Article
Language:English
Published: Elsevier 2023-02-01
Series:Catalysis Communications
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Online Access:http://www.sciencedirect.com/science/article/pii/S1566736723000274
Description
Summary:Nowadays, 2-methylfuran is urgently needed especially in pharmaceutical manufacture. However, the direct synthesis of 2-methylfuran via the efficient dehydration and hydrogenation of xylose usually requires a multistep reaction. Herein, a route of tandem conversion xylose to 2-methylfuran was developed. The xylose was firstly converted into furfural by Hβ zeolite, followed by the catalysis of furfural to 2-methylfuran over 0.5NiCu/C. Compared with two-step reaction, cascade strategy applied xylose conversion improved the 2-methylfuran yield rate by 41.5%. In general, this work expanded the application of tandem method for the enhancement of xylose effective conversion and provided a new biomass utilization technology.
ISSN:1873-3905