Gold-catalyzed alkylation of silyl enol ethers with ortho-alkynylbenzoic acid esters

Unprecedented alkylation of silyl enol ethers has been developed by the use of ortho-alkynylbenzoic acid alkyl esters as alkylating agents in the presence of a gold catalyst. The reaction probably proceeds through the gold-induced in situ construction of leaving groups and subsequent nucleophilic at...

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Bibliographic Details
Main Authors: Haruo Aikawa, Tetsuro Kaneko, Naoki Asao, Yoshinori Yamamoto
Format: Article
Language:English
Published: Beilstein-Institut 2011-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.7.76

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