Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate
The iminodiacetate dianion in the title compound, [Zn(C4H5NO4)(C12H8N2)(H2O)]·1.5H2O, chelates to the ZnII center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianio...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808042141 |
| _version_ | 1818905346374107136 |
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| author | Hwa Loong Ng Chew Hee Ng Seik Weng Ng |
| author_facet | Hwa Loong Ng Chew Hee Ng Seik Weng Ng |
| author_sort | Hwa Loong Ng |
| collection | DOAJ |
| description | The iminodiacetate dianion in the title compound, [Zn(C4H5NO4)(C12H8N2)(H2O)]·1.5H2O, chelates to the ZnII center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water molecules interact through O—H...O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water molecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component. |
| first_indexed | 2024-12-19T21:21:52Z |
| format | Article |
| id | doaj.art-79d90a0c85904f92bcb2030fd03321f1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:21:52Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-79d90a0c85904f92bcb2030fd03321f12022-12-21T20:05:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m89m8910.1107/S1600536808042141Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrateHwa Loong NgChew Hee NgSeik Weng NgThe iminodiacetate dianion in the title compound, [Zn(C4H5NO4)(C12H8N2)(H2O)]·1.5H2O, chelates to the ZnII center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water molecules interact through O—H...O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water molecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component.http://scripts.iucr.org/cgi-bin/paper?S1600536808042141 |
| spellingShingle | Hwa Loong Ng Chew Hee Ng Seik Weng Ng Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate Acta Crystallographica Section E |
| title | Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate |
| title_full | Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate |
| title_fullStr | Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate |
| title_full_unstemmed | Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate |
| title_short | Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) sesquihydrate |
| title_sort | aqua iminodiacetato 954 3o n o 8242 1 10 phenanthroline 954 2n n 8242 zinc ii sesquihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808042141 |
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