Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance

Experimental approaches are employed for the understanding of oxygen permeation through membranes. For the experiments, different oxygen partial pressures are applied to both sides of a BSCF5582 membrane, using synthetic air as feed and vacuum or steam/argon as sweep gas. Beside the partial pressure...

Full description

Bibliographic Details
Main Authors: Michael Müller, Robert Spatschek, Florian Thaler
Format: Article
Language:English
Published: AIMS Press 2016-08-01
Series:AIMS Materials Science
Subjects:
Online Access:http://www.aimspress.com/Materials/article/911/fulltext.html
_version_ 1819226931788251136
author Michael Müller
Robert Spatschek
Florian Thaler
author_facet Michael Müller
Robert Spatschek
Florian Thaler
author_sort Michael Müller
collection DOAJ
description Experimental approaches are employed for the understanding of oxygen permeation through membranes. For the experiments, different oxygen partial pressures are applied to both sides of a BSCF5582 membrane, using synthetic air as feed and vacuum or steam/argon as sweep gas. Beside the partial pressure gradient, the permeation rate depends on the temperature and the membrane thickness. Sufficient permeation rates can be achieved by sweeping the membrane with water vapor (steam) instead of a noble gas, which is optimized by ascending water content in the sweep gas. The influence of the steam content on the permeation performance as well as microstructural changes are demonstrated.
first_indexed 2024-12-23T10:33:20Z
format Article
id doaj.art-79df0967ec3d4bff835ef0f4a5a69ee3
institution Directory Open Access Journal
issn 2372-0484
language English
last_indexed 2024-12-23T10:33:20Z
publishDate 2016-08-01
publisher AIMS Press
record_format Article
series AIMS Materials Science
spelling doaj.art-79df0967ec3d4bff835ef0f4a5a69ee32022-12-21T17:50:22ZengAIMS PressAIMS Materials Science2372-04842016-08-01331126113710.3934/matersci.2016.3.1126matersci-03-01126Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performanceMichael Müller0Robert Spatschek1Florian Thaler2Forschungszentrum Jülich, Institute of Energy and Climate Research – IEK-2, 52425 Jülich, GermanyForschungszentrum Jülich, Institute of Energy and Climate Research – IEK-2, 52425 Jülich, GermanyForschungszentrum Jülich, Institute of Energy and Climate Research – IEK-2, 52425 Jülich, GermanyExperimental approaches are employed for the understanding of oxygen permeation through membranes. For the experiments, different oxygen partial pressures are applied to both sides of a BSCF5582 membrane, using synthetic air as feed and vacuum or steam/argon as sweep gas. Beside the partial pressure gradient, the permeation rate depends on the temperature and the membrane thickness. Sufficient permeation rates can be achieved by sweeping the membrane with water vapor (steam) instead of a noble gas, which is optimized by ascending water content in the sweep gas. The influence of the steam content on the permeation performance as well as microstructural changes are demonstrated.http://www.aimspress.com/Materials/article/911/fulltext.htmlperovskiteoxygen transport membraneBSCFpermeation measurementsteam sweep
spellingShingle Michael Müller
Robert Spatschek
Florian Thaler
Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance
AIMS Materials Science
perovskite
oxygen transport membrane
BSCF
permeation measurement
steam sweep
title Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance
title_full Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance
title_fullStr Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance
title_full_unstemmed Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance
title_short Oxygen permeation through perovskitic membranes: The influence of steam in the sweep on the permeation performance
title_sort oxygen permeation through perovskitic membranes the influence of steam in the sweep on the permeation performance
topic perovskite
oxygen transport membrane
BSCF
permeation measurement
steam sweep
url http://www.aimspress.com/Materials/article/911/fulltext.html
work_keys_str_mv AT michaelmuller oxygenpermeationthroughperovskiticmembranestheinfluenceofsteaminthesweeponthepermeationperformance
AT robertspatschek oxygenpermeationthroughperovskiticmembranestheinfluenceofsteaminthesweeponthepermeationperformance
AT florianthaler oxygenpermeationthroughperovskiticmembranestheinfluenceofsteaminthesweeponthepermeationperformance