The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process

Pesticide compounds can influence denitrification processes in groundwater in many ways. This study observed behavior of three selected pesticides under denitrifying conditions. Alachlor, terbuthylazine, and tebuconazole, in a concentration of 0.1 mL L<sup>−1</sup>, were examined using t...

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Main Authors: Kristína Pániková, Zuzana Bílková, Jitka Malá
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Journal of Xenobiotics
Subjects:
Online Access:https://www.mdpi.com/2039-4713/13/4/36
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author Kristína Pániková
Zuzana Bílková
Jitka Malá
author_facet Kristína Pániková
Zuzana Bílková
Jitka Malá
author_sort Kristína Pániková
collection DOAJ
description Pesticide compounds can influence denitrification processes in groundwater in many ways. This study observed behavior of three selected pesticides under denitrifying conditions. Alachlor, terbuthylazine, and tebuconazole, in a concentration of 0.1 mL L<sup>−1</sup>, were examined using two laboratory denitrifications assays: a “short” 7-day and a “long” 28-day test. During these tests, removal of pesticides via adsorption and biotic decomposition, as well as the efficiency of nitrate removal in the presence of the pesticides, were measured. No considerable inhibition of the denitrification process was observed for any of the pesticides. On the contrary, significant stimulation was observed after 21 days for alachlor (49%) and after seven days for terbuthylazine (40%) and tebuconazole (36%). Adsorption was in progress only during the first seven days in the case of all tested pesticides and increased only negligibly afterwards. Immediate adsorption of terbuthylazine was probably influenced by the mercuric chloride inhibitor. A biotic loss of 4% was measured only in the case of alachlor.
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spelling doaj.art-79e146a285d84d1a8c1283fe5f557ed02023-12-22T14:19:41ZengMDPI AGJournal of Xenobiotics2039-47052039-47132023-10-0113456057110.3390/jox13040036The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification ProcessKristína Pániková0Zuzana Bílková1Jitka Malá2Institute of Chemistry, Faculty of Civil Engineering, Brno University of Technology, 602 00 Brno, Czech RepublicResearch Centre for Toxic Compounds in the Environment, Faculty of Science, Masaryk University, 611 37 Brno, Czech RepublicInstitute of Chemistry, Faculty of Civil Engineering, Brno University of Technology, 602 00 Brno, Czech RepublicPesticide compounds can influence denitrification processes in groundwater in many ways. This study observed behavior of three selected pesticides under denitrifying conditions. Alachlor, terbuthylazine, and tebuconazole, in a concentration of 0.1 mL L<sup>−1</sup>, were examined using two laboratory denitrifications assays: a “short” 7-day and a “long” 28-day test. During these tests, removal of pesticides via adsorption and biotic decomposition, as well as the efficiency of nitrate removal in the presence of the pesticides, were measured. No considerable inhibition of the denitrification process was observed for any of the pesticides. On the contrary, significant stimulation was observed after 21 days for alachlor (49%) and after seven days for terbuthylazine (40%) and tebuconazole (36%). Adsorption was in progress only during the first seven days in the case of all tested pesticides and increased only negligibly afterwards. Immediate adsorption of terbuthylazine was probably influenced by the mercuric chloride inhibitor. A biotic loss of 4% was measured only in the case of alachlor.https://www.mdpi.com/2039-4713/13/4/36alachlorterbuthylazinetebuconazoleinhibitionlaboratory denitrification assay
spellingShingle Kristína Pániková
Zuzana Bílková
Jitka Malá
The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
Journal of Xenobiotics
alachlor
terbuthylazine
tebuconazole
inhibition
laboratory denitrification assay
title The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
title_full The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
title_fullStr The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
title_full_unstemmed The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
title_short The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
title_sort behavior of terbuthylazine tebuconazole and alachlor during denitrification process
topic alachlor
terbuthylazine
tebuconazole
inhibition
laboratory denitrification assay
url https://www.mdpi.com/2039-4713/13/4/36
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