The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process
Pesticide compounds can influence denitrification processes in groundwater in many ways. This study observed behavior of three selected pesticides under denitrifying conditions. Alachlor, terbuthylazine, and tebuconazole, in a concentration of 0.1 mL L<sup>−1</sup>, were examined using t...
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MDPI AG
2023-10-01
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Online Access: | https://www.mdpi.com/2039-4713/13/4/36 |
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author | Kristína Pániková Zuzana Bílková Jitka Malá |
author_facet | Kristína Pániková Zuzana Bílková Jitka Malá |
author_sort | Kristína Pániková |
collection | DOAJ |
description | Pesticide compounds can influence denitrification processes in groundwater in many ways. This study observed behavior of three selected pesticides under denitrifying conditions. Alachlor, terbuthylazine, and tebuconazole, in a concentration of 0.1 mL L<sup>−1</sup>, were examined using two laboratory denitrifications assays: a “short” 7-day and a “long” 28-day test. During these tests, removal of pesticides via adsorption and biotic decomposition, as well as the efficiency of nitrate removal in the presence of the pesticides, were measured. No considerable inhibition of the denitrification process was observed for any of the pesticides. On the contrary, significant stimulation was observed after 21 days for alachlor (49%) and after seven days for terbuthylazine (40%) and tebuconazole (36%). Adsorption was in progress only during the first seven days in the case of all tested pesticides and increased only negligibly afterwards. Immediate adsorption of terbuthylazine was probably influenced by the mercuric chloride inhibitor. A biotic loss of 4% was measured only in the case of alachlor. |
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language | English |
last_indexed | 2024-03-08T20:36:54Z |
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spelling | doaj.art-79e146a285d84d1a8c1283fe5f557ed02023-12-22T14:19:41ZengMDPI AGJournal of Xenobiotics2039-47052039-47132023-10-0113456057110.3390/jox13040036The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification ProcessKristína Pániková0Zuzana Bílková1Jitka Malá2Institute of Chemistry, Faculty of Civil Engineering, Brno University of Technology, 602 00 Brno, Czech RepublicResearch Centre for Toxic Compounds in the Environment, Faculty of Science, Masaryk University, 611 37 Brno, Czech RepublicInstitute of Chemistry, Faculty of Civil Engineering, Brno University of Technology, 602 00 Brno, Czech RepublicPesticide compounds can influence denitrification processes in groundwater in many ways. This study observed behavior of three selected pesticides under denitrifying conditions. Alachlor, terbuthylazine, and tebuconazole, in a concentration of 0.1 mL L<sup>−1</sup>, were examined using two laboratory denitrifications assays: a “short” 7-day and a “long” 28-day test. During these tests, removal of pesticides via adsorption and biotic decomposition, as well as the efficiency of nitrate removal in the presence of the pesticides, were measured. No considerable inhibition of the denitrification process was observed for any of the pesticides. On the contrary, significant stimulation was observed after 21 days for alachlor (49%) and after seven days for terbuthylazine (40%) and tebuconazole (36%). Adsorption was in progress only during the first seven days in the case of all tested pesticides and increased only negligibly afterwards. Immediate adsorption of terbuthylazine was probably influenced by the mercuric chloride inhibitor. A biotic loss of 4% was measured only in the case of alachlor.https://www.mdpi.com/2039-4713/13/4/36alachlorterbuthylazinetebuconazoleinhibitionlaboratory denitrification assay |
spellingShingle | Kristína Pániková Zuzana Bílková Jitka Malá The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process Journal of Xenobiotics alachlor terbuthylazine tebuconazole inhibition laboratory denitrification assay |
title | The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process |
title_full | The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process |
title_fullStr | The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process |
title_full_unstemmed | The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process |
title_short | The Behavior of Terbuthylazine, Tebuconazole, and Alachlor during Denitrification Process |
title_sort | behavior of terbuthylazine tebuconazole and alachlor during denitrification process |
topic | alachlor terbuthylazine tebuconazole inhibition laboratory denitrification assay |
url | https://www.mdpi.com/2039-4713/13/4/36 |
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