Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries

The morphology of Zinc (Zn) deposits was investigated as anode for aqueous batteries. The Zn was deposited from zinc sulfate solution in direct current conditions on a copper surface at different current densities. The morphology characterization of Zn deposits was performed via field emission scann...

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Main Authors: Nurhaswani Alias, Ahmad Azmin Mohamad
Format: Article
Language:English
Published: Elsevier 2015-01-01
Series:Journal of King Saud University: Engineering Sciences
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1018363913000111
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author Nurhaswani Alias
Ahmad Azmin Mohamad
author_facet Nurhaswani Alias
Ahmad Azmin Mohamad
author_sort Nurhaswani Alias
collection DOAJ
description The morphology of Zinc (Zn) deposits was investigated as anode for aqueous batteries. The Zn was deposited from zinc sulfate solution in direct current conditions on a copper surface at different current densities. The morphology characterization of Zn deposits was performed via field emission scanning electron microscopy. The Zn deposits transformed from a dense and compact structure to dendritic form with increasing current density. The electrodeposition of Zn with a current density of 0.02 A cm−2 exhibited good morphology with a high charge efficiency that reached up to 95.2%. The Zn deposits were applied as the anode in zinc–air and zinc–carbon batteries, which gave specific discharge capacities of 460 and 300 mA h g−1, respectively.
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spelling doaj.art-79e1f7d0d03f4c30bdb066c8238a8fae2022-12-22T02:08:41ZengElsevierJournal of King Saud University: Engineering Sciences1018-36392015-01-01271434810.1016/j.jksues.2013.03.003Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteriesNurhaswani AliasAhmad Azmin MohamadThe morphology of Zinc (Zn) deposits was investigated as anode for aqueous batteries. The Zn was deposited from zinc sulfate solution in direct current conditions on a copper surface at different current densities. The morphology characterization of Zn deposits was performed via field emission scanning electron microscopy. The Zn deposits transformed from a dense and compact structure to dendritic form with increasing current density. The electrodeposition of Zn with a current density of 0.02 A cm−2 exhibited good morphology with a high charge efficiency that reached up to 95.2%. The Zn deposits were applied as the anode in zinc–air and zinc–carbon batteries, which gave specific discharge capacities of 460 and 300 mA h g−1, respectively.http://www.sciencedirect.com/science/article/pii/S1018363913000111Zn depositionCopper substrateCurrent densityZinc-air batteryZinc-carbon battery
spellingShingle Nurhaswani Alias
Ahmad Azmin Mohamad
Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries
Journal of King Saud University: Engineering Sciences
Zn deposition
Copper substrate
Current density
Zinc-air battery
Zinc-carbon battery
title Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries
title_full Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries
title_fullStr Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries
title_full_unstemmed Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries
title_short Morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc-air and zinc-carbon batteries
title_sort morphology study of electrodeposited zinc from zinc sulfate solutions as anode for zinc air and zinc carbon batteries
topic Zn deposition
Copper substrate
Current density
Zinc-air battery
Zinc-carbon battery
url http://www.sciencedirect.com/science/article/pii/S1018363913000111
work_keys_str_mv AT nurhaswanialias morphologystudyofelectrodepositedzincfromzincsulfatesolutionsasanodeforzincairandzinccarbonbatteries
AT ahmadazminmohamad morphologystudyofelectrodepositedzincfromzincsulfatesolutionsasanodeforzincairandzinccarbonbatteries