A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO

Glasses with compositions (100-x) % Na2B4O7–x % MO (X=10,20,30,40) where (M) is Ba, Mg and Ca, are prepared using conventional melt quenching method. X-rays diffractions are performed. The result of (XRD) confirm the amorphous nature of the samples. The measured density increases with increasing con...

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Main Authors: Aynur Bahaaldeen kamal, Manaf al-azzawi
Format: Article
Language:Arabic
Published: College of Education for Pure Sciences 2021-03-01
Series:مجلة التربية والعلم
Subjects:
Online Access:https://edusj.mosuljournals.com/article_166187_0676eab76948d16ee316941fb808713a.pdf
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author Aynur Bahaaldeen kamal
Manaf al-azzawi
author_facet Aynur Bahaaldeen kamal
Manaf al-azzawi
author_sort Aynur Bahaaldeen kamal
collection DOAJ
description Glasses with compositions (100-x) % Na2B4O7–x % MO (X=10,20,30,40) where (M) is Ba, Mg and Ca, are prepared using conventional melt quenching method. X-rays diffractions are performed. The result of (XRD) confirm the amorphous nature of the samples. The measured density increases with increasing content of BaO, MgO & CaO in glass network. The position and shifting rate of absorption edge, optical band energy (Eopt) and band tails energy (Eo) were investigated. The Eopt and Eo values of all glasses studied in this work were found to be comparable with the values corresponding to some semiconductors. The structure of the glasses was investigated by means of IR spectroscopy. It found from the experimental results of IR spectra that the groups (BO3)- and (B2O7)- are dominant the structure of these glasses. Also It is found that the shifting in band position is small with increasing of (Ba, Mg, Ca) oxide in the glass network.
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spelling doaj.art-79e923c1ac154ce1bbe698c20114cf5e2022-12-21T22:20:44ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25302021-03-01301102310.33899/edusj.2020.127127.1076166187A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaOAynur Bahaaldeen kamal0Manaf al-azzawi1Physics , College of Education for Pure Sciences , Unversity of Kirkuk , Kirkuk , IraqDepartment of Physics, College of Education for Pure Sciences, University of Kirkuk, Kirkuk, IraqGlasses with compositions (100-x) % Na2B4O7–x % MO (X=10,20,30,40) where (M) is Ba, Mg and Ca, are prepared using conventional melt quenching method. X-rays diffractions are performed. The result of (XRD) confirm the amorphous nature of the samples. The measured density increases with increasing content of BaO, MgO & CaO in glass network. The position and shifting rate of absorption edge, optical band energy (Eopt) and band tails energy (Eo) were investigated. The Eopt and Eo values of all glasses studied in this work were found to be comparable with the values corresponding to some semiconductors. The structure of the glasses was investigated by means of IR spectroscopy. It found from the experimental results of IR spectra that the groups (BO3)- and (B2O7)- are dominant the structure of these glasses. Also It is found that the shifting in band position is small with increasing of (Ba, Mg, Ca) oxide in the glass network.https://edusj.mosuljournals.com/article_166187_0676eab76948d16ee316941fb808713a.pdfoptical band energy (eopt),,,،,؛spectroscopy for infrared absorption (ir),,,،,؛x-rays diffreactions (xrd).,,,،,؛band tails energy (eo)
spellingShingle Aynur Bahaaldeen kamal
Manaf al-azzawi
A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO
مجلة التربية والعلم
optical band energy (eopt),,
,،,؛spectroscopy for infrared absorption (ir),,
,،,؛x-rays diffreactions (xrd).,,
,،,؛band tails energy (eo)
title A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO
title_full A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO
title_fullStr A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO
title_full_unstemmed A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO
title_short A Study of Optical Properties of Tetraborate Glasses Containing CaO, MgO & BaO
title_sort study of optical properties of tetraborate glasses containing cao mgo bao
topic optical band energy (eopt),,
,،,؛spectroscopy for infrared absorption (ir),,
,،,؛x-rays diffreactions (xrd).,,
,،,؛band tails energy (eo)
url https://edusj.mosuljournals.com/article_166187_0676eab76948d16ee316941fb808713a.pdf
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