Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge

Various pretreatment methods have been combined and employed for maximizing the solubilization of waste-activated sludge (WAS). However, the question “by changing the series of applied combined pretreatments (CPs), can the solubilization efficiency of WAS be affected?” has never been addressed. In t...

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Main Authors: Alsayed Mostafa, Min-Gyun Kim, Seongwon Im, Mo-Kwon Lee, Seoktae Kang, Dong-Hoon Kim
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/16/4165
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author Alsayed Mostafa
Min-Gyun Kim
Seongwon Im
Mo-Kwon Lee
Seoktae Kang
Dong-Hoon Kim
author_facet Alsayed Mostafa
Min-Gyun Kim
Seongwon Im
Mo-Kwon Lee
Seoktae Kang
Dong-Hoon Kim
author_sort Alsayed Mostafa
collection DOAJ
description Various pretreatment methods have been combined and employed for maximizing the solubilization of waste-activated sludge (WAS). However, the question “by changing the series of applied combined pretreatments (CPs), can the solubilization efficiency of WAS be affected?” has never been addressed. In this study, firstly, thermal (T), alkaline (A), and ultrasonic (U) pretreatments were individually applied at broad strengths (T = 80–120 °C for 30 min, A = pH 9–12, and U = 5–60 min at 300 W). Then, pretreatment conditions that caused similar solubilization (13.0%) (120 °C, pH 11, and 30 min for T, A, and U, respectively), were adopted for CP with reverse sequences of T&A, U&A, and T&U. A similar disintegration degree was observed in U→A and A→U, while a meaningful difference was found in T&A and T&U: T→A (28.3%), A→T (42.9%), T→U (22.9%), and U→T (27.1%). The difference in pretreatment series also affected the characteristics of soluble matters, which was analyzed by excitation emission matrix and molecular weight distribution. Due to these differences, the highest methane yield of 68.8% (based on (chemical oxygen demand) COD<sub>input</sub>) was achieved at A→T, compared to T→A (62.3%). Our results suggested a simple strategy for increasing solubilization, at the same expense of energy, which might be beneficial in the following treatment process, such as dewatering and transportation.
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spelling doaj.art-79f087a2cd66418e94afd41c4e4d4cb62023-11-20T09:52:38ZengMDPI AGEnergies1996-10732020-08-011316416510.3390/en13164165Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated SludgeAlsayed Mostafa0Min-Gyun Kim1Seongwon Im2Mo-Kwon Lee3Seoktae Kang4Dong-Hoon Kim5Department of Civil Engineering, Inha University, 100 Inharo, Nam-gu, Incheon 22212, KoreaDepartment of Civil Engineering, Inha University, 100 Inharo, Nam-gu, Incheon 22212, KoreaDepartment of Civil Engineering, Inha University, 100 Inharo, Nam-gu, Incheon 22212, KoreaDepartment of Civil Engineering, Inha University, 100 Inharo, Nam-gu, Incheon 22212, KoreaDepartment of Civil and Environmental Engineering, KAIST, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, KoreaDepartment of Civil Engineering, Inha University, 100 Inharo, Nam-gu, Incheon 22212, KoreaVarious pretreatment methods have been combined and employed for maximizing the solubilization of waste-activated sludge (WAS). However, the question “by changing the series of applied combined pretreatments (CPs), can the solubilization efficiency of WAS be affected?” has never been addressed. In this study, firstly, thermal (T), alkaline (A), and ultrasonic (U) pretreatments were individually applied at broad strengths (T = 80–120 °C for 30 min, A = pH 9–12, and U = 5–60 min at 300 W). Then, pretreatment conditions that caused similar solubilization (13.0%) (120 °C, pH 11, and 30 min for T, A, and U, respectively), were adopted for CP with reverse sequences of T&A, U&A, and T&U. A similar disintegration degree was observed in U→A and A→U, while a meaningful difference was found in T&A and T&U: T→A (28.3%), A→T (42.9%), T→U (22.9%), and U→T (27.1%). The difference in pretreatment series also affected the characteristics of soluble matters, which was analyzed by excitation emission matrix and molecular weight distribution. Due to these differences, the highest methane yield of 68.8% (based on (chemical oxygen demand) COD<sub>input</sub>) was achieved at A→T, compared to T→A (62.3%). Our results suggested a simple strategy for increasing solubilization, at the same expense of energy, which might be beneficial in the following treatment process, such as dewatering and transportation.https://www.mdpi.com/1996-1073/13/16/4165combined pretreatmentsequencewaste-activated sludgesolubilizationmethane yieldanaerobic digestion
spellingShingle Alsayed Mostafa
Min-Gyun Kim
Seongwon Im
Mo-Kwon Lee
Seoktae Kang
Dong-Hoon Kim
Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge
Energies
combined pretreatment
sequence
waste-activated sludge
solubilization
methane yield
anaerobic digestion
title Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge
title_full Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge
title_fullStr Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge
title_full_unstemmed Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge
title_short Series of Combined Pretreatment Can Affect the Solubilization of Waste-Activated Sludge
title_sort series of combined pretreatment can affect the solubilization of waste activated sludge
topic combined pretreatment
sequence
waste-activated sludge
solubilization
methane yield
anaerobic digestion
url https://www.mdpi.com/1996-1073/13/16/4165
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