Naturally Nano: Magnetically Separable Nanocomposites from Natural Resources for Advanced Catalytic Applications

The present manuscript describes the use of silk cocoons as a structuring agent for the formation of an iron-based active phase for the controlled oxidation of benzyl alcohol. Different samples were prepared using different calcination temperatures. X-ray diffraction and transmission electron micros...

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Bibliographic Details
Main Authors: Rick A. D. Arancon, Zeid A. Al Othman, Thomas Len, Kaimin Shih, Leonid Voskressensky, Rafael Luque
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/12/11/1337
Description
Summary:The present manuscript describes the use of silk cocoons as a structuring agent for the formation of an iron-based active phase for the controlled oxidation of benzyl alcohol. Different samples were prepared using different calcination temperatures. X-ray diffraction and transmission electron microscopy showed a higher proportion of alpha-Fe<sub>2</sub>O<sub>3</sub> phase and a higher global crystallinity at superior calcination temperature. In terms of catalytic activity, the sample treated at 500 °C presented the highest conversion reaching 47%, with selectivity in benzaldehyde of 75.9%.
ISSN:2073-4344