Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots

The Ti element plays a role in pinning grain boundaries but also has a good binding ability to C and N, forming large primary carbides. Therefore, the effect of Ti content on primary carbides’ behavior in H13 ingots was comprehensively studied. A non-aqueous electrolysis method was used to determine...

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Main Authors: Yu Huang, Guoguang Cheng, Meiting Zhu
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/6/837
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author Yu Huang
Guoguang Cheng
Meiting Zhu
author_facet Yu Huang
Guoguang Cheng
Meiting Zhu
author_sort Yu Huang
collection DOAJ
description The Ti element plays a role in pinning grain boundaries but also has a good binding ability to C and N, forming large primary carbides. Therefore, the effect of Ti content on primary carbides’ behavior in H13 ingots was comprehensively studied. A non-aqueous electrolysis method was used to determine the three-dimensional (3D) characteristics of primary carbides. We found a great difference between the two-dimensional (2D) and the three-dimensional characteristics of primary carbides. When performing 2D analyses, the density of the primary carbides appeared high, while their size was small. The actual characteristics of primary carbides can be obtained only by 3D observation. The primary carbide showed a typical dendritic structure, whose center consisted of Ti–V-rich carbide wrapped by V-rich carbide. As the Ti content increased, the size of the primary carbide increased from 24.9 μm to 41.3 μm, and the number density increases from 25.6 per/mm<sup>2</sup> to 43.9 per/mm<sup>2</sup>. The Ti4C2S2 phase precipitated first, then changed into Ti–V-rich carbide, and finally further partly transformed into V-rich carbide. The addition of elemental Ti promoted the precipitation and transformation of primary carbides, resulting in an increase of the number density and size.
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spelling doaj.art-7a14d9f3073b4edf9fbfeac6d8d851992023-11-20T04:50:45ZengMDPI AGMetals2075-47012020-06-0110683710.3390/met10060837Effect of Ti Content on the Behavior of Primary Carbides in H13 IngotsYu Huang0Guoguang Cheng1Meiting Zhu2State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Xueyuan Road NO.30, Beijing 100083, ChinaState Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Xueyuan Road NO.30, Beijing 100083, ChinaTianjin College, University of Science and Technology Beijing, Zhujiang North Ring East Road NO.1, Baodi District, Tianjin 301830, ChinaThe Ti element plays a role in pinning grain boundaries but also has a good binding ability to C and N, forming large primary carbides. Therefore, the effect of Ti content on primary carbides’ behavior in H13 ingots was comprehensively studied. A non-aqueous electrolysis method was used to determine the three-dimensional (3D) characteristics of primary carbides. We found a great difference between the two-dimensional (2D) and the three-dimensional characteristics of primary carbides. When performing 2D analyses, the density of the primary carbides appeared high, while their size was small. The actual characteristics of primary carbides can be obtained only by 3D observation. The primary carbide showed a typical dendritic structure, whose center consisted of Ti–V-rich carbide wrapped by V-rich carbide. As the Ti content increased, the size of the primary carbide increased from 24.9 μm to 41.3 μm, and the number density increases from 25.6 per/mm<sup>2</sup> to 43.9 per/mm<sup>2</sup>. The Ti4C2S2 phase precipitated first, then changed into Ti–V-rich carbide, and finally further partly transformed into V-rich carbide. The addition of elemental Ti promoted the precipitation and transformation of primary carbides, resulting in an increase of the number density and size.https://www.mdpi.com/2075-4701/10/6/837Ti contentH13 steelprimary carbidethree-dimensional morphology
spellingShingle Yu Huang
Guoguang Cheng
Meiting Zhu
Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots
Metals
Ti content
H13 steel
primary carbide
three-dimensional morphology
title Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots
title_full Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots
title_fullStr Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots
title_full_unstemmed Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots
title_short Effect of Ti Content on the Behavior of Primary Carbides in H13 Ingots
title_sort effect of ti content on the behavior of primary carbides in h13 ingots
topic Ti content
H13 steel
primary carbide
three-dimensional morphology
url https://www.mdpi.com/2075-4701/10/6/837
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