Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions

The use of cold spray deposition, coupled with diffusion-driven thermal postprocessing, is considered herein as a surface modification process such that near-surface microstructural, micromechanical, and microchemical property improvements can be procured for cost-effective and common aluminum alloy...

Full description

Bibliographic Details
Main Authors: Alino Te, Bryer C. Sousa, Brajendra Mishra, Danielle L. Cote
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/3/432
_version_ 1797413393228890112
author Alino Te
Bryer C. Sousa
Brajendra Mishra
Danielle L. Cote
author_facet Alino Te
Bryer C. Sousa
Brajendra Mishra
Danielle L. Cote
author_sort Alino Te
collection DOAJ
description The use of cold spray deposition, coupled with diffusion-driven thermal postprocessing, is considered herein as a surface modification process such that near-surface microstructural, micromechanical, and microchemical property improvements can be procured for cost-effective and common aluminum alloy castings. Since the present work was an exploratory investigation into the realm of cold spray induced, high-pressure diecast aluminum subsurface property development and evolution, as well as surface modification, one significant aim was to formalize a set of fundamental observations for continued consideration of such an approach to achieving premium aluminum alloy properties from cost-effective alternatives. Nickel, copper, and titanium cold spray modified near-surface regions of the cost-effective high-pressure diecast A365 system was considered. Near-surface, subsurface, and surface evolution was documented across each of the three pure metal coatings. The analysis was continued across two postprocessing coating-substrate atomic diffusion inspired heat-treated conditions as well. Using energy-dispersive X-ray spectroscopy, field-emission scanning electron microscopy, optical microscopy, and various insights gleaned from an original contextualization of the relevant cold spray literature, noteworthy results were recorded and discussed herein. When copper feedstock was employed alongside thermal postprocessing, diverse surface-based intermetallic compounds formed alongside exotic diffusion zones and severely oxidized regions, thus eliminating thermally activated copper cold-sprayed consolidations from future work too. However, both nickel and titanium cold spray surface modification processing demonstrated potential and promise if correct processing stages were performed directly and chronologically. Consequently, a platform is presented for further research on cold sprayed surface microstructural and property modification of cost-effective alloyed aluminum castings.
first_indexed 2024-03-09T05:17:14Z
format Article
id doaj.art-7a1578d40c85424ca16d9358a4c57ec8
institution Directory Open Access Journal
issn 2075-4701
language English
last_indexed 2024-03-09T05:17:14Z
publishDate 2021-03-01
publisher MDPI AG
record_format Article
series Metals
spelling doaj.art-7a1578d40c85424ca16d9358a4c57ec82023-12-03T12:44:39ZengMDPI AGMetals2075-47012021-03-0111343210.3390/met11030432Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated ConditionsAlino Te0Bryer C. Sousa1Brajendra Mishra2Danielle L. Cote3Materials & Manufacturing Engineering, Worcester Polytechnic Institute, Worcester, MA 01609, USAMaterials & Manufacturing Engineering, Worcester Polytechnic Institute, Worcester, MA 01609, USAMaterials & Manufacturing Engineering, Worcester Polytechnic Institute, Worcester, MA 01609, USAMaterials & Manufacturing Engineering, Worcester Polytechnic Institute, Worcester, MA 01609, USAThe use of cold spray deposition, coupled with diffusion-driven thermal postprocessing, is considered herein as a surface modification process such that near-surface microstructural, micromechanical, and microchemical property improvements can be procured for cost-effective and common aluminum alloy castings. Since the present work was an exploratory investigation into the realm of cold spray induced, high-pressure diecast aluminum subsurface property development and evolution, as well as surface modification, one significant aim was to formalize a set of fundamental observations for continued consideration of such an approach to achieving premium aluminum alloy properties from cost-effective alternatives. Nickel, copper, and titanium cold spray modified near-surface regions of the cost-effective high-pressure diecast A365 system was considered. Near-surface, subsurface, and surface evolution was documented across each of the three pure metal coatings. The analysis was continued across two postprocessing coating-substrate atomic diffusion inspired heat-treated conditions as well. Using energy-dispersive X-ray spectroscopy, field-emission scanning electron microscopy, optical microscopy, and various insights gleaned from an original contextualization of the relevant cold spray literature, noteworthy results were recorded and discussed herein. When copper feedstock was employed alongside thermal postprocessing, diverse surface-based intermetallic compounds formed alongside exotic diffusion zones and severely oxidized regions, thus eliminating thermally activated copper cold-sprayed consolidations from future work too. However, both nickel and titanium cold spray surface modification processing demonstrated potential and promise if correct processing stages were performed directly and chronologically. Consequently, a platform is presented for further research on cold sprayed surface microstructural and property modification of cost-effective alloyed aluminum castings.https://www.mdpi.com/2075-4701/11/3/432high-pressure die-castingalloyed aluminumcold spray processingalloy surface modificationintermetallic compoundsbimetallic systems and processing
spellingShingle Alino Te
Bryer C. Sousa
Brajendra Mishra
Danielle L. Cote
Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions
Metals
high-pressure die-casting
alloyed aluminum
cold spray processing
alloy surface modification
intermetallic compounds
bimetallic systems and processing
title Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions
title_full Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions
title_fullStr Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions
title_full_unstemmed Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions
title_short Subsurface Microstructural Evolution of High-Pressure Diecast A365: From Cast to Cold-Sprayed and Heat-Treated Conditions
title_sort subsurface microstructural evolution of high pressure diecast a365 from cast to cold sprayed and heat treated conditions
topic high-pressure die-casting
alloyed aluminum
cold spray processing
alloy surface modification
intermetallic compounds
bimetallic systems and processing
url https://www.mdpi.com/2075-4701/11/3/432
work_keys_str_mv AT alinote subsurfacemicrostructuralevolutionofhighpressurediecasta365fromcasttocoldsprayedandheattreatedconditions
AT bryercsousa subsurfacemicrostructuralevolutionofhighpressurediecasta365fromcasttocoldsprayedandheattreatedconditions
AT brajendramishra subsurfacemicrostructuralevolutionofhighpressurediecasta365fromcasttocoldsprayedandheattreatedconditions
AT daniellelcote subsurfacemicrostructuralevolutionofhighpressurediecasta365fromcasttocoldsprayedandheattreatedconditions