Geopolymer materials based on natural zeolite

One of the potential raw materials for preparation of geopolymers is the natural zeolite. In the present report, the used natural zeolite (clinoptilolite) is from huge deposit near Beli Plast, Bulgaria. Geopolymer pastes and mortars are prepared by using three different alkaline activators—sodium hy...

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Main Authors: Aleksandar Nikolov, Ivan Rostovsky, Henk Nugteren
Format: Article
Language:English
Published: Elsevier 2017-06-01
Series:Case Studies in Construction Materials
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S221450951630064X
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author Aleksandar Nikolov
Ivan Rostovsky
Henk Nugteren
author_facet Aleksandar Nikolov
Ivan Rostovsky
Henk Nugteren
author_sort Aleksandar Nikolov
collection DOAJ
description One of the potential raw materials for preparation of geopolymers is the natural zeolite. In the present report, the used natural zeolite (clinoptilolite) is from huge deposit near Beli Plast, Bulgaria. Geopolymer pastes and mortars are prepared by using three different alkaline activators—sodium hydroxide, sodium silicate and sodium carbonate. The hardened geopolymers are tested for determination of mechanical properties by traditional standardized methods. The structure and the composition of the materials are studied by direct physical methods—X-ray diffraction (XRD), thermal analysis (DTA and TGA) and scanning electron microscopy (SEM). The results show variable degree of dissolutions of the raw zeolite material when using different activators and formation of solid geopolymer materials with qualitatively different structure. Despite its relatively low compressive strength, geopolymers based on natural zeolite cured at room temperature and used as coating, show very good adhesion to concrete.
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spelling doaj.art-7a15fcd32fef4b149255dbda8d2628f32022-12-22T03:52:27ZengElsevierCase Studies in Construction Materials2214-50952017-06-016C19820510.1016/j.cscm.2017.03.001Geopolymer materials based on natural zeoliteAleksandar Nikolov0Ivan Rostovsky1Henk Nugteren2Department of Building Materials and Insulations, Faculty of Civil Engineering, University of Architecture, Civil Engineering and Geodesy, blvd. “Hristo Smirnenski” 1, Sofia, BulgariaDepartment of Building Materials and Insulations, Faculty of Civil Engineering, University of Architecture, Civil Engineering and Geodesy, blvd. “Hristo Smirnenski” 1, Sofia, BulgariaSection Product and Process Engineering, Department of Chemical Engineering, Delft University of Technology, Delft, The NetherlandsOne of the potential raw materials for preparation of geopolymers is the natural zeolite. In the present report, the used natural zeolite (clinoptilolite) is from huge deposit near Beli Plast, Bulgaria. Geopolymer pastes and mortars are prepared by using three different alkaline activators—sodium hydroxide, sodium silicate and sodium carbonate. The hardened geopolymers are tested for determination of mechanical properties by traditional standardized methods. The structure and the composition of the materials are studied by direct physical methods—X-ray diffraction (XRD), thermal analysis (DTA and TGA) and scanning electron microscopy (SEM). The results show variable degree of dissolutions of the raw zeolite material when using different activators and formation of solid geopolymer materials with qualitatively different structure. Despite its relatively low compressive strength, geopolymers based on natural zeolite cured at room temperature and used as coating, show very good adhesion to concrete.http://www.sciencedirect.com/science/article/pii/S221450951630064XGeopolymerNatural zeoliteClinoptilolite
spellingShingle Aleksandar Nikolov
Ivan Rostovsky
Henk Nugteren
Geopolymer materials based on natural zeolite
Case Studies in Construction Materials
Geopolymer
Natural zeolite
Clinoptilolite
title Geopolymer materials based on natural zeolite
title_full Geopolymer materials based on natural zeolite
title_fullStr Geopolymer materials based on natural zeolite
title_full_unstemmed Geopolymer materials based on natural zeolite
title_short Geopolymer materials based on natural zeolite
title_sort geopolymer materials based on natural zeolite
topic Geopolymer
Natural zeolite
Clinoptilolite
url http://www.sciencedirect.com/science/article/pii/S221450951630064X
work_keys_str_mv AT aleksandarnikolov geopolymermaterialsbasedonnaturalzeolite
AT ivanrostovsky geopolymermaterialsbasedonnaturalzeolite
AT henknugteren geopolymermaterialsbasedonnaturalzeolite