Ozonolysis of long-chain cyclic acetals: formation of monoesters
A procedure is described for the quantitative conversion of saturated long-chain cyclic acetals of diols to the corresponding O-acyl diols. Acetal ozonolysis proceeds in ethyl acetate–methylene chloride solution at –16 to –18°C without overoxidation.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
1974-09-01
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| Series: | Journal of Lipid Research |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S0022227520367742 |
| _version_ | 1818650968096505856 |
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| author | W.J. Baumann T.H. Madson |
| author_facet | W.J. Baumann T.H. Madson |
| author_sort | W.J. Baumann |
| collection | DOAJ |
| description | A procedure is described for the quantitative conversion of saturated long-chain cyclic acetals of diols to the corresponding O-acyl diols. Acetal ozonolysis proceeds in ethyl acetate–methylene chloride solution at –16 to –18°C without overoxidation. |
| first_indexed | 2024-12-17T01:58:38Z |
| format | Article |
| id | doaj.art-7a2f6cdccadf4d8eaa892e257e5b03ab |
| institution | Directory Open Access Journal |
| issn | 0022-2275 |
| language | English |
| last_indexed | 2024-12-17T01:58:38Z |
| publishDate | 1974-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Lipid Research |
| spelling | doaj.art-7a2f6cdccadf4d8eaa892e257e5b03ab2022-12-21T22:07:53ZengElsevierJournal of Lipid Research0022-22751974-09-01155528529Ozonolysis of long-chain cyclic acetals: formation of monoestersW.J. Baumann0T.H. Madson1University of Minnesota, The Hormel Institute, Austin, Minnesota 55912University of Minnesota, The Hormel Institute, Austin, Minnesota 55912A procedure is described for the quantitative conversion of saturated long-chain cyclic acetals of diols to the corresponding O-acyl diols. Acetal ozonolysis proceeds in ethyl acetate–methylene chloride solution at –16 to –18°C without overoxidation.http://www.sciencedirect.com/science/article/pii/S0022227520367742diol cyclic acetalsdiol monoestersester synthesisoxidative acetal cleavage |
| spellingShingle | W.J. Baumann T.H. Madson Ozonolysis of long-chain cyclic acetals: formation of monoesters Journal of Lipid Research diol cyclic acetals diol monoesters ester synthesis oxidative acetal cleavage |
| title | Ozonolysis of long-chain cyclic acetals: formation of monoesters |
| title_full | Ozonolysis of long-chain cyclic acetals: formation of monoesters |
| title_fullStr | Ozonolysis of long-chain cyclic acetals: formation of monoesters |
| title_full_unstemmed | Ozonolysis of long-chain cyclic acetals: formation of monoesters |
| title_short | Ozonolysis of long-chain cyclic acetals: formation of monoesters |
| title_sort | ozonolysis of long chain cyclic acetals formation of monoesters |
| topic | diol cyclic acetals diol monoesters ester synthesis oxidative acetal cleavage |
| url | http://www.sciencedirect.com/science/article/pii/S0022227520367742 |
| work_keys_str_mv | AT wjbaumann ozonolysisoflongchaincyclicacetalsformationofmonoesters AT thmadson ozonolysisoflongchaincyclicacetalsformationofmonoesters |