{N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II)
The central NiII atom in the title complex, [Ni(C16H13BrN2O2)(C5H5N)], is in a square-planar trans-N2O2 environment defined by the NO2 donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine molecule forms a dihedral angle of 9.99 (11)&#...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811029114 |
| _version_ | 1818959491193896960 |
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| author | Chang-Zheng Zheng Liang Wang Juan Liu Yu-Jie Wang |
| author_facet | Chang-Zheng Zheng Liang Wang Juan Liu Yu-Jie Wang |
| author_sort | Chang-Zheng Zheng |
| collection | DOAJ |
| description | The central NiII atom in the title complex, [Ni(C16H13BrN2O2)(C5H5N)], is in a square-planar trans-N2O2 environment defined by the NO2 donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine molecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN2O2 atoms. |
| first_indexed | 2024-12-20T11:42:29Z |
| format | Article |
| id | doaj.art-7a2fe354d28c46f7945288189a4d99ba |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:42:29Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7a2fe354d28c46f7945288189a4d99ba2022-12-21T19:41:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1132m113210.1107/S1600536811029114{N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II)Chang-Zheng ZhengLiang WangJuan LiuYu-Jie WangThe central NiII atom in the title complex, [Ni(C16H13BrN2O2)(C5H5N)], is in a square-planar trans-N2O2 environment defined by the NO2 donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine molecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN2O2 atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536811029114 |
| spellingShingle | Chang-Zheng Zheng Liang Wang Juan Liu Yu-Jie Wang {N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II) Acta Crystallographica Section E |
| title | {N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II) |
| title_full | {N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II) |
| title_fullStr | {N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II) |
| title_full_unstemmed | {N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II) |
| title_short | {N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2N′,O}(pyridine-κN)nickel(II) |
| title_sort | n amp 8242 e 1 5 bromo 2 oxidophenyl ethylidene amp 954 o 4 methylbenzohydrazidato amp 954 2n amp 8242 o pyridine amp 954 n nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811029114 |
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