CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation

Here, we present the preparation of composites with green persistent luminescence using melting process. The composites are phosphate glass (75NaPO3-25CaF2 and 90NaPO3-10NaF (in mol%)) with embedded phosphors: CaWO4: Yb3+, Tm3+ crystals with blue upconversion and SrAl2O4:Eu2+,Dy3+ with green persist...

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Main Authors: Santos Magalhães Evellyn, Sedda Ahmed, Bondzior Bartosz., Vuori Sami, Van der Heggen David, Smet Philippe F., Lastusaari Mika, Petit Laeticia
Format: Article
Language:English
Published: EDP Sciences 2023-01-01
Series:EPJ Web of Conferences
Online Access:https://www.epj-conferences.org/articles/epjconf/pdf/2023/13/epjconf_eosam2023_05043.pdf
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author Santos Magalhães Evellyn
Sedda Ahmed
Bondzior Bartosz.
Vuori Sami
Van der Heggen David
Smet Philippe F.
Lastusaari Mika
Petit Laeticia
author_facet Santos Magalhães Evellyn
Sedda Ahmed
Bondzior Bartosz.
Vuori Sami
Van der Heggen David
Smet Philippe F.
Lastusaari Mika
Petit Laeticia
author_sort Santos Magalhães Evellyn
collection DOAJ
description Here, we present the preparation of composites with green persistent luminescence using melting process. The composites are phosphate glass (75NaPO3-25CaF2 and 90NaPO3-10NaF (in mol%)) with embedded phosphors: CaWO4: Yb3+, Tm3+ crystals with blue upconversion and SrAl2O4:Eu2+,Dy3+ with green persistent luminescence. Green persistent luminescence above 0.3 mcd/m2 can be seen for ~ 30 minutes after charging with 980 nm due to energy transfer between the blue upconverter crystals and the persistent luminescent phosphors. Challenges related to the fabrication of such composites are discussed.
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spelling doaj.art-7a3608693d774383bb67ae88bc9ef6112023-11-07T10:20:48ZengEDP SciencesEPJ Web of Conferences2100-014X2023-01-012870504310.1051/epjconf/202328705043epjconf_eosam2023_05043CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR ExcitationSantos Magalhães Evellyn0Sedda Ahmed1Bondzior Bartosz.2Vuori Sami3Van der Heggen David4Smet Philippe F.5Lastusaari Mika6Petit Laeticia7Photonics Laboratory, Tampere UniversityPhotonics Laboratory, Tampere UniversityPhotonics Laboratory, Tampere UniversityDepartment of Chemistry, University of TurkuLumiLab, Department of Solid State Sciences, Ghent UniversityLumiLab, Department of Solid State Sciences, Ghent UniversityDepartment of Chemistry, University of TurkuPhotonics Laboratory, Tampere UniversityHere, we present the preparation of composites with green persistent luminescence using melting process. The composites are phosphate glass (75NaPO3-25CaF2 and 90NaPO3-10NaF (in mol%)) with embedded phosphors: CaWO4: Yb3+, Tm3+ crystals with blue upconversion and SrAl2O4:Eu2+,Dy3+ with green persistent luminescence. Green persistent luminescence above 0.3 mcd/m2 can be seen for ~ 30 minutes after charging with 980 nm due to energy transfer between the blue upconverter crystals and the persistent luminescent phosphors. Challenges related to the fabrication of such composites are discussed.https://www.epj-conferences.org/articles/epjconf/pdf/2023/13/epjconf_eosam2023_05043.pdf
spellingShingle Santos Magalhães Evellyn
Sedda Ahmed
Bondzior Bartosz.
Vuori Sami
Van der Heggen David
Smet Philippe F.
Lastusaari Mika
Petit Laeticia
CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
EPJ Web of Conferences
title CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
title_full CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
title_fullStr CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
title_full_unstemmed CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
title_short CaWO4:Yb3+,Tm3+ Crystals and SrAl2O4:Eu2+,Dy3+ Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
title_sort cawo4 yb3 tm3 crystals and sral2o4 eu2 dy3 phosphors in glass based composites for green afterglow after nir excitation
url https://www.epj-conferences.org/articles/epjconf/pdf/2023/13/epjconf_eosam2023_05043.pdf
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