Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study
This work provides new insight into the development of the TiO2/Oxone/UV-LED process for organic contaminant degradation as well as hospital waste management. The Moxifloxacin (MOX) degradation using Oxone activated TiO2 under UV-LED was studied. The TiO2/Oxone/UV LED process was carried out by the...
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| Format: | Article |
| Language: | English |
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Elsevier
2022-09-01
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| Series: | Arabian Journal of Chemistry |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S187853522200377X |
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| author | Muhammad Imran Kanjal Majid Muneer Muhammad Saeed Wei Chu Norah Alwadai Munawar Iqbal Amal Abdelhaleem |
| author_facet | Muhammad Imran Kanjal Majid Muneer Muhammad Saeed Wei Chu Norah Alwadai Munawar Iqbal Amal Abdelhaleem |
| author_sort | Muhammad Imran Kanjal |
| collection | DOAJ |
| description | This work provides new insight into the development of the TiO2/Oxone/UV-LED process for organic contaminant degradation as well as hospital waste management. The Moxifloxacin (MOX) degradation using Oxone activated TiO2 under UV-LED was studied. The TiO2/Oxone/UV LED process was carried out by the addition of Oxone (0.025, 0.05, 0.1 and 0.2 mM) activated by TiO2 different concentrations 0.0125, 0.025, 0.05, 0.1 and 0.5 g/L. The degradation efficiency was studied by HPLC having UV/Vis detector, C18 column (5µ, 4.6 × 250 mm2). The complete removal of 10 ppm of MOX occurred at 0.1 g/L TiO2 and 0.1 mM Oxone with UV-LED exposure time of 12 min. The TOC analysis was performed and 55% TOC reduction was observed at described procedure. The parameters such as drug initial concentration, Oxone, TiO2 dosages and pH were optimized and their effects on degradation were noted. The pseudo-first order reaction kinetics was observed for MOX degradation. It was revealed from the mechanism of activation that SO4-. and OH. have played a key role in the degradation. The effect of pH (3.6–11) was observed to evaluate the degradation rate of Moxifloxacin. The pH 9.4 achieved the maximum degradation. The UPLC-ESI-MS analysis was performed to identify the intermediates and degraded end-products. |
| first_indexed | 2024-04-13T04:43:25Z |
| format | Article |
| id | doaj.art-7a3dc3c5f337484788ba98fc0319c53f |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-04-13T04:43:25Z |
| publishDate | 2022-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-7a3dc3c5f337484788ba98fc0319c53f2022-12-22T03:01:56ZengElsevierArabian Journal of Chemistry1878-53522022-09-01159104061Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic studyMuhammad Imran Kanjal0Majid Muneer1Muhammad Saeed2Wei Chu3Norah Alwadai4Munawar Iqbal5Amal Abdelhaleem6Department of Chemistry, Government College University, Faisalabad 38000, Pakistan; Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong KongDepartment of Chemistry, Government College University, Faisalabad 38000, Pakistan; Corresponding authors.Department of Chemistry, Government College University, Faisalabad 38000, PakistanDepartment of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong KongDepartment of Physics, College of Sciences, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi ArabiaDepartment of Chemistry, Division of Science and Technology, University of Education, Lahore, Pakistan; Corresponding authors.Environmental Engineering Department, Egypt-Japan University of Science and Technology, New Borg El-Arab City, Alexandria 21934, EgyptThis work provides new insight into the development of the TiO2/Oxone/UV-LED process for organic contaminant degradation as well as hospital waste management. The Moxifloxacin (MOX) degradation using Oxone activated TiO2 under UV-LED was studied. The TiO2/Oxone/UV LED process was carried out by the addition of Oxone (0.025, 0.05, 0.1 and 0.2 mM) activated by TiO2 different concentrations 0.0125, 0.025, 0.05, 0.1 and 0.5 g/L. The degradation efficiency was studied by HPLC having UV/Vis detector, C18 column (5µ, 4.6 × 250 mm2). The complete removal of 10 ppm of MOX occurred at 0.1 g/L TiO2 and 0.1 mM Oxone with UV-LED exposure time of 12 min. The TOC analysis was performed and 55% TOC reduction was observed at described procedure. The parameters such as drug initial concentration, Oxone, TiO2 dosages and pH were optimized and their effects on degradation were noted. The pseudo-first order reaction kinetics was observed for MOX degradation. It was revealed from the mechanism of activation that SO4-. and OH. have played a key role in the degradation. The effect of pH (3.6–11) was observed to evaluate the degradation rate of Moxifloxacin. The pH 9.4 achieved the maximum degradation. The UPLC-ESI-MS analysis was performed to identify the intermediates and degraded end-products.http://www.sciencedirect.com/science/article/pii/S187853522200377XMoxifloxacinPhotocatalytic degradationUV-LEDAdvanced Oxidation Process |
| spellingShingle | Muhammad Imran Kanjal Majid Muneer Muhammad Saeed Wei Chu Norah Alwadai Munawar Iqbal Amal Abdelhaleem Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study Arabian Journal of Chemistry Moxifloxacin Photocatalytic degradation UV-LED Advanced Oxidation Process |
| title | Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study |
| title_full | Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study |
| title_fullStr | Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study |
| title_full_unstemmed | Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study |
| title_short | Oxone activated TiO2 in presence of UV-LED light for the degradation of moxifloxacin: A mechanistic study |
| title_sort | oxone activated tio2 in presence of uv led light for the degradation of moxifloxacin a mechanistic study |
| topic | Moxifloxacin Photocatalytic degradation UV-LED Advanced Oxidation Process |
| url | http://www.sciencedirect.com/science/article/pii/S187853522200377X |
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