Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde
Theoretical analysis of the possibility of conjugating the reaction of formaldehyde formation via dehydrogenation of methanol with other initiating reactions is conducted; and advantages of using hydrogen peroxide vs. organic inductors are discussed. When hydrogen peroxide is used, the reaction reac...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2009-12-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1040 |
| _version_ | 1826565848938053632 |
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| author | V. F. Tretyakov A. M. Ilolov R. M. Talyshinsky N. A. Frantsuzova A. S. Popov |
| author_facet | V. F. Tretyakov A. M. Ilolov R. M. Talyshinsky N. A. Frantsuzova A. S. Popov |
| author_sort | V. F. Tretyakov |
| collection | DOAJ |
| description | Theoretical analysis of the possibility of conjugating the reaction of formaldehyde formation via dehydrogenation of methanol with other initiating reactions is conducted; and advantages of using hydrogen peroxide vs. organic inductors are discussed. When hydrogen peroxide is used, the reaction reaches stationary condition almost immediately. It is demonstrated that the induction and the targeted reaction proceed with high selectivity towards formaldehyde. |
| first_indexed | 2024-04-10T03:31:59Z |
| format | Article |
| id | doaj.art-7a3f97a74ee9442e99bd1b56082bf99d |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2025-03-14T10:42:17Z |
| publishDate | 2009-12-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-7a3f97a74ee9442e99bd1b56082bf99d2025-03-02T10:57:25ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752009-12-014683841034Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehydeV. F. Tretyakov0A. M. Ilolov1R. M. Talyshinsky2N. A. Frantsuzova3A. S. Popov4Moscow Technological University (Institute of Fine Chemical Technologies), 86, Vernadskogo pr., Moscow 119571Moscow Technological University (Institute of Fine Chemical Technologies), 86, Vernadskogo pr., Moscow 119571Институт нефтехимического синтеза им. А.В. Топчиева РАНMoscow Technological University (Institute of Fine Chemical Technologies), 86, Vernadskogo pr., Moscow 119571Институт нефтехимического синтеза им. А.В. Топчиева РАНTheoretical analysis of the possibility of conjugating the reaction of formaldehyde formation via dehydrogenation of methanol with other initiating reactions is conducted; and advantages of using hydrogen peroxide vs. organic inductors are discussed. When hydrogen peroxide is used, the reaction reaches stationary condition almost immediately. It is demonstrated that the induction and the targeted reaction proceed with high selectivity towards formaldehyde.https://www.finechem-mirea.ru/jour/article/view/1040dehydrogenation, methanol, formaldehyde, thermodynamic analysis, kinetic analysis, interface reactions |
| spellingShingle | V. F. Tretyakov A. M. Ilolov R. M. Talyshinsky N. A. Frantsuzova A. S. Popov Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde Тонкие химические технологии dehydrogenation, methanol, formaldehyde, thermodynamic analysis, kinetic analysis, interface reactions |
| title | Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde |
| title_full | Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde |
| title_fullStr | Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde |
| title_full_unstemmed | Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde |
| title_short | Thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde |
| title_sort | thermodynamic and kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde |
| topic | dehydrogenation, methanol, formaldehyde, thermodynamic analysis, kinetic analysis, interface reactions |
| url | https://www.finechem-mirea.ru/jour/article/view/1040 |
| work_keys_str_mv | AT vftretyakov thermodynamicandkineticanalysisofthechemicalreactionofmethanoldehydrationtoformaldehyde AT amilolov thermodynamicandkineticanalysisofthechemicalreactionofmethanoldehydrationtoformaldehyde AT rmtalyshinsky thermodynamicandkineticanalysisofthechemicalreactionofmethanoldehydrationtoformaldehyde AT nafrantsuzova thermodynamicandkineticanalysisofthechemicalreactionofmethanoldehydrationtoformaldehyde AT aspopov thermodynamicandkineticanalysisofthechemicalreactionofmethanoldehydrationtoformaldehyde |