3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors

The increasing interest in wearable devices for health monitoring, illness prevention, and human motion detection has driven research towards developing novel and cost-effective solutions for highly sensitive flexible sensors. The objective of this work is to develop innovative piezoresistive pressu...

Full description

Bibliographic Details
Main Authors: Marco Fortunato, Luca Pacitto, Nicola Pesce, Alessio Tamburrano
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/23/16/7054
_version_ 1797583282344296448
author Marco Fortunato
Luca Pacitto
Nicola Pesce
Alessio Tamburrano
author_facet Marco Fortunato
Luca Pacitto
Nicola Pesce
Alessio Tamburrano
author_sort Marco Fortunato
collection DOAJ
description The increasing interest in wearable devices for health monitoring, illness prevention, and human motion detection has driven research towards developing novel and cost-effective solutions for highly sensitive flexible sensors. The objective of this work is to develop innovative piezoresistive pressure sensors utilizing two types of 3D porous flexible open-cell foams: Grid and triply periodic minimal surface structures. These foams will be produced through a procedure involving the 3D printing of sacrificial templates, followed by infiltration with various low-viscosity polymers, leaching, and ultimately coating the pores with graphene nanoplatelets (GNPs). Additive manufacturing enables precise control over the shape and dimensions of the structure by manipulating geometric parameters during the design phase. This control extends to the piezoresistive response of the sensors, which is achieved by infiltrating the foams with varying concentrations of a colloidal suspension of GNPs. To examine the morphology of the produced materials, field emission scanning electron microscopy (FE-SEM) is employed, while mechanical and piezoresistive behavior are investigated through quasi-static uniaxial compression tests. The results obtained indicate that the optimized grid-based structure sensors, manufactured using the commercial polymer Solaris, exhibit the highest sensitivity compared to other tested samples. These sensors demonstrate a maximum sensitivity of 0.088 kPa<sup>−1</sup> for pressures below 10 kPa, increasing to 0.24 kPa<sup>−1</sup> for pressures of 80 kPa. Furthermore, the developed sensors are successfully applied to measure heartbeats both before and after aerobic activity, showcasing their excellent sensitivity within the typical pressure range exerted by the heartbeat, which typically falls between 10 and 20 kPa.
first_indexed 2024-03-10T23:36:41Z
format Article
id doaj.art-7a41e024920844dcaff5124a7b159800
institution Directory Open Access Journal
issn 1424-8220
language English
last_indexed 2024-03-10T23:36:41Z
publishDate 2023-08-01
publisher MDPI AG
record_format Article
series Sensors
spelling doaj.art-7a41e024920844dcaff5124a7b1598002023-11-19T02:56:08ZengMDPI AGSensors1424-82202023-08-012316705410.3390/s231670543D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure SensorsMarco Fortunato0Luca Pacitto1Nicola Pesce2Alessio Tamburrano3Department of Astronautical, Electrical and Energy Engineering (DIAEE), Sapienza University of Rome, 00184 Rome, ItalyDepartment of Astronautical, Electrical and Energy Engineering (DIAEE), Sapienza University of Rome, 00184 Rome, ItalyDepartment of Astronautical, Electrical and Energy Engineering (DIAEE), Sapienza University of Rome, 00184 Rome, ItalyDepartment of Astronautical, Electrical and Energy Engineering (DIAEE), Sapienza University of Rome, 00184 Rome, ItalyThe increasing interest in wearable devices for health monitoring, illness prevention, and human motion detection has driven research towards developing novel and cost-effective solutions for highly sensitive flexible sensors. The objective of this work is to develop innovative piezoresistive pressure sensors utilizing two types of 3D porous flexible open-cell foams: Grid and triply periodic minimal surface structures. These foams will be produced through a procedure involving the 3D printing of sacrificial templates, followed by infiltration with various low-viscosity polymers, leaching, and ultimately coating the pores with graphene nanoplatelets (GNPs). Additive manufacturing enables precise control over the shape and dimensions of the structure by manipulating geometric parameters during the design phase. This control extends to the piezoresistive response of the sensors, which is achieved by infiltrating the foams with varying concentrations of a colloidal suspension of GNPs. To examine the morphology of the produced materials, field emission scanning electron microscopy (FE-SEM) is employed, while mechanical and piezoresistive behavior are investigated through quasi-static uniaxial compression tests. The results obtained indicate that the optimized grid-based structure sensors, manufactured using the commercial polymer Solaris, exhibit the highest sensitivity compared to other tested samples. These sensors demonstrate a maximum sensitivity of 0.088 kPa<sup>−1</sup> for pressures below 10 kPa, increasing to 0.24 kPa<sup>−1</sup> for pressures of 80 kPa. Furthermore, the developed sensors are successfully applied to measure heartbeats both before and after aerobic activity, showcasing their excellent sensitivity within the typical pressure range exerted by the heartbeat, which typically falls between 10 and 20 kPa.https://www.mdpi.com/1424-8220/23/16/70543D printingfoampressure sensorgraphenenanoplateletspiezoresistivity
spellingShingle Marco Fortunato
Luca Pacitto
Nicola Pesce
Alessio Tamburrano
3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors
Sensors
3D printing
foam
pressure sensor
graphene
nanoplatelets
piezoresistivity
title 3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors
title_full 3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors
title_fullStr 3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors
title_full_unstemmed 3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors
title_short 3D-Printed Graphene Nanoplatelets/Polymer Foams for Low/Medium-Pressure Sensors
title_sort 3d printed graphene nanoplatelets polymer foams for low medium pressure sensors
topic 3D printing
foam
pressure sensor
graphene
nanoplatelets
piezoresistivity
url https://www.mdpi.com/1424-8220/23/16/7054
work_keys_str_mv AT marcofortunato 3dprintedgraphenenanoplateletspolymerfoamsforlowmediumpressuresensors
AT lucapacitto 3dprintedgraphenenanoplateletspolymerfoamsforlowmediumpressuresensors
AT nicolapesce 3dprintedgraphenenanoplateletspolymerfoamsforlowmediumpressuresensors
AT alessiotamburrano 3dprintedgraphenenanoplateletspolymerfoamsforlowmediumpressuresensors