Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole
The complex formation of the ion-pair formed between the anionic chelate of Ge(IV)‒4-nitrocatechol (4-NC) and the cation of 1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazole (Nitron, Nt) in the liquid-liquid extraction system Ge(IV)‒4-NC‒Nt‒H2O‒CHCl3 was studied by spectrophotometry. The optimum extrac...
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2017-06-01
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| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/3214 |
| _version_ | 1818498651364786176 |
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| author | Petya Racheva Kirila Stojnova Vidka Divarova Vanya Lekova |
| author_facet | Petya Racheva Kirila Stojnova Vidka Divarova Vanya Lekova |
| author_sort | Petya Racheva |
| collection | DOAJ |
| description | The complex formation of the ion-pair formed between the anionic chelate of Ge(IV)‒4-nitrocatechol (4-NC) and the cation of 1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazole (Nitron, Nt) in the liquid-liquid extraction system Ge(IV)‒4-NC‒Nt‒H2O‒CHCl3 was studied by spectrophotometry. The optimum extraction-spectrophotometric conditions for the complex formation were established. The validity of Beer’s law was checked and some analytical characteristics of the system were calculated. The effect of co-existing ions and reagents on the process of complex formation was investigated. The association process in aqueous phase and the extraction equilibria were studied and quantitatively characterized. The following key constants of the processes were calculated: association constant, distribution constant, extraction constant and recovery factor. The molar ratio of the reagents was determined by independent methods. A reaction scheme and a general formula of the complex were suggested. |
| first_indexed | 2024-12-10T20:18:28Z |
| format | Article |
| id | doaj.art-7a4a01f3c35d44caa723f9ea31dd31dc |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-10T20:18:28Z |
| publishDate | 2017-06-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-7a4a01f3c35d44caa723f9ea31dd31dc2022-12-22T01:35:07ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552017-06-0164236537210.17344/acsi.2017.3214461Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazolePetya Racheva0Kirila Stojnova1Vidka Divarova2Vanya Lekova3Medical University-Plovdiv, 15AVasil Aprilov Boulevard, 4002 Plovdiv, BulgariaPlovdiv University, 24 Tzar Assen St, 4000 Plovdiv, BulgariaMedical University-Plovdiv, 15AVasil Aprilov Boulevard, 4002 Plovdiv, BulgariaPlovdiv University. 24 Tzar Assen St, 4000 Plovdiv, BulgariaThe complex formation of the ion-pair formed between the anionic chelate of Ge(IV)‒4-nitrocatechol (4-NC) and the cation of 1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazole (Nitron, Nt) in the liquid-liquid extraction system Ge(IV)‒4-NC‒Nt‒H2O‒CHCl3 was studied by spectrophotometry. The optimum extraction-spectrophotometric conditions for the complex formation were established. The validity of Beer’s law was checked and some analytical characteristics of the system were calculated. The effect of co-existing ions and reagents on the process of complex formation was investigated. The association process in aqueous phase and the extraction equilibria were studied and quantitatively characterized. The following key constants of the processes were calculated: association constant, distribution constant, extraction constant and recovery factor. The molar ratio of the reagents was determined by independent methods. A reaction scheme and a general formula of the complex were suggested.https://journals.matheo.si/index.php/ACSi/article/view/3214germanium(IV)nitronion-pairchelate formationextraction equilibriums |
| spellingShingle | Petya Racheva Kirila Stojnova Vidka Divarova Vanya Lekova Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole Acta Chimica Slovenica germanium(IV) nitron ion-pair chelate formation extraction equilibriums |
| title | Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole |
| title_full | Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole |
| title_fullStr | Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole |
| title_full_unstemmed | Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole |
| title_short | Study on the Equilibria of the Complex Formation of the Ion-pair of Germanium(IV) with 4-Nitrocatechol and 1,4-Diphenyl-3-(phenylamino)-1H-1,2,4-triazole |
| title_sort | study on the equilibria of the complex formation of the ion pair of germanium iv with 4 nitrocatechol and 1 4 diphenyl 3 phenylamino 1h 1 2 4 triazole |
| topic | germanium(IV) nitron ion-pair chelate formation extraction equilibriums |
| url | https://journals.matheo.si/index.php/ACSi/article/view/3214 |
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