Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site

The spatial distribution, migration characteristics, and ecological risks of heavy metals in manganese (Mn) contaminated sites were studied by field investigation and geostatistical analysis. In this study, surface soil samples were collected from an Mn mine wasteland and the soil in this area was p...

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Main Authors: Yangtao Lv, Gilbert Kabanda, Yueru Chen, Chuan Wu, Waichin Li
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-09-01
Series:Frontiers in Environmental Science
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fenvs.2022.942544/full
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author Yangtao Lv
Gilbert Kabanda
Yueru Chen
Chuan Wu
Chuan Wu
Waichin Li
author_facet Yangtao Lv
Gilbert Kabanda
Yueru Chen
Chuan Wu
Chuan Wu
Waichin Li
author_sort Yangtao Lv
collection DOAJ
description The spatial distribution, migration characteristics, and ecological risks of heavy metals in manganese (Mn) contaminated sites were studied by field investigation and geostatistical analysis. In this study, surface soil samples were collected from an Mn mine wasteland and the soil in this area was polluted by Mn, Pb, Cu, Cd, Zn, and Cr, and the corresponding element concentrations were 16.3, 15.4, 15.0, 9.90, 6.10, and 1.1 times of the limited standard, respectively. In addition, the soil in different samples in the same region has obvious heterogeneity. By using X-ray fluorescence spectrometry (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS), the heavy metal concentrations in soil samples were determined. ICP-MS corroborated XRF for soil heavy metal determination and showed that XRF was a reliable and quick alternative for heavy metal determination in soil. To discover heavy metal distribution trends, distribution maps of heavy metals were created using the Kriging interpolation method. The geoaccumulation index (Igeo), improved Nemerow index (INI), and potential ecological risk index (RI) was used to assess the pollution degree and the environmental risk of metal pollution in the study area. The contamination degree of heavy metal is Mn > Cd > Pb > Zn > Cu > Cr. The spatial distribution and risk assessment of heavy metals in manganese contaminated sites will help to monitor the migration trajectory of heavy metals in mining areas and protect the soil from long-term accumulation of heavy metals. It provides the basis for heavy metal pollution remediation strategy and ecological risk management.
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spelling doaj.art-7a514e5b77f74614bbe61a3933fc54432022-12-22T04:23:00ZengFrontiers Media S.A.Frontiers in Environmental Science2296-665X2022-09-011010.3389/fenvs.2022.942544942544Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated siteYangtao Lv0Gilbert Kabanda1Yueru Chen2Chuan Wu3Chuan Wu4Waichin Li5School of Metallurgy and Environment, Central South University, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, Changsha, ChinaDepartment of Science and Environmental Studies, The Education University of Hong Kong, Tai Po, ChinaDepartment of Science and Environmental Studies, The Education University of Hong Kong, Tai Po, ChinaThe spatial distribution, migration characteristics, and ecological risks of heavy metals in manganese (Mn) contaminated sites were studied by field investigation and geostatistical analysis. In this study, surface soil samples were collected from an Mn mine wasteland and the soil in this area was polluted by Mn, Pb, Cu, Cd, Zn, and Cr, and the corresponding element concentrations were 16.3, 15.4, 15.0, 9.90, 6.10, and 1.1 times of the limited standard, respectively. In addition, the soil in different samples in the same region has obvious heterogeneity. By using X-ray fluorescence spectrometry (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS), the heavy metal concentrations in soil samples were determined. ICP-MS corroborated XRF for soil heavy metal determination and showed that XRF was a reliable and quick alternative for heavy metal determination in soil. To discover heavy metal distribution trends, distribution maps of heavy metals were created using the Kriging interpolation method. The geoaccumulation index (Igeo), improved Nemerow index (INI), and potential ecological risk index (RI) was used to assess the pollution degree and the environmental risk of metal pollution in the study area. The contamination degree of heavy metal is Mn > Cd > Pb > Zn > Cu > Cr. The spatial distribution and risk assessment of heavy metals in manganese contaminated sites will help to monitor the migration trajectory of heavy metals in mining areas and protect the soil from long-term accumulation of heavy metals. It provides the basis for heavy metal pollution remediation strategy and ecological risk management.https://www.frontiersin.org/articles/10.3389/fenvs.2022.942544/fullmanganese (Mn) contaminated sitesoilheavy metalgeoaccumulation indexecological risk index
spellingShingle Yangtao Lv
Gilbert Kabanda
Yueru Chen
Chuan Wu
Chuan Wu
Waichin Li
Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site
Frontiers in Environmental Science
manganese (Mn) contaminated site
soil
heavy metal
geoaccumulation index
ecological risk index
title Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site
title_full Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site
title_fullStr Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site
title_full_unstemmed Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site
title_short Spatial distribution and ecological risk assessment of heavy metals in manganese (Mn) contaminated site
title_sort spatial distribution and ecological risk assessment of heavy metals in manganese mn contaminated site
topic manganese (Mn) contaminated site
soil
heavy metal
geoaccumulation index
ecological risk index
url https://www.frontiersin.org/articles/10.3389/fenvs.2022.942544/full
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