Copper Isotopes and Constraints on the Ore Genesis Process of Cu-Co Ore Deposits at the Idaho Cobalt Belt, USA

Quantifying and identifying the introduction of metal in ore deposits that have experienced multiple overprinting hydrothermal events remains an elusive yet essential goal in metallogenic studies. Here, we constrain the origin of Co in the Idaho Cobalt Belt (ICB) that experienced two distinct metal-...

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Bibliographic Details
Main Authors: Nina Zaronikola, Elizabeth A. Holley, Ryan Mathur, Dan Pace
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/11/1355
Description
Summary:Quantifying and identifying the introduction of metal in ore deposits that have experienced multiple overprinting hydrothermal events remains an elusive yet essential goal in metallogenic studies. Here, we constrain the origin of Co in the Idaho Cobalt Belt (ICB) that experienced two distinct metal-rich events that introduced Co and Cu. We performed a detailed petrographic study of sulfide ore at Iron Creek in the ICB, in concert with the quantification of trace metal element concentrations and copper isotope values to identify the introduction of Co in the system. The pyrite displays various degrees of alteration, with the highest Co concentrations (up to 6 wt.%) in less-altered pyrite grains (e.g., sharp edges, absence of altered boundaries and fissures) and highest <i>δ</i><sup>65</sup>Cu isotope value. The most-altered pyrite grains (e.g., corroded grains, round and altered boundaries) have lower Co contents and lower <i>δ</i><sup>65</sup>Cu isotope values that match the copper isotope values of the chalcopyrite. The least-altered pyrite shows a narrow <i>δ</i><sup>65</sup>Cu range between −0.39‰ to −0.58‰. In contrast, the most-altered pyrite grains are isotopically depleted, showing a <i>δ</i><sup>65</sup>Cu range from −1.35‰ to −0.90‰. Chalcopyrite shows a <i>δ</i><sup>65</sup>Cu range between −1.07‰ and −0.77‰. We interpret, from the Cu isotope compositions and Co concentrations in pyrite, that the Co was originally introduced into the siliciclastic host rock package in a Mesoproterozoic SEDEX environment. The heavier Cu was then preferentially leached in a second event, resulting in isotopically lighter Cu in the altered pyrite. Remobilization of the SEDEX cobalt was likely associated with CO<sub>2</sub>-rich metamorphic fluids present in the region during the Mesoproterozoic East Kootenay orogeny, the late Mesoproterozoic Grenville orogeny, and the Late Jurassic to Late Cretaceous Cordilleran orogeny.
ISSN:2075-163X