Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production
Imazalil is a chiral fungicide widely used to protect strawberries against gray mold, which may pose threats to food safety. This study aims to investigate the stereoselective behavior of imazalil during strawberry growth and strawberry wine production. A method was proposed and validated for the ex...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-01-01
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| Series: | Journal of Food Protection |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S0362028X22000059 |
| _version_ | 1797774620897574912 |
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| author | Jia Zhang Wei Jiang Zhihang Jia Wenjie Zhang Ting Zhang Meng Wei |
| author_facet | Jia Zhang Wei Jiang Zhihang Jia Wenjie Zhang Ting Zhang Meng Wei |
| author_sort | Jia Zhang |
| collection | DOAJ |
| description | Imazalil is a chiral fungicide widely used to protect strawberries against gray mold, which may pose threats to food safety. This study aims to investigate the stereoselective behavior of imazalil during strawberry growth and strawberry wine production. A method was proposed and validated for the extraction and quantitative analysis of imazalil residues in strawberry, strawberry pomace, and strawberry wine by using ultra-high performance liquid chromatography-tandem mass spectrometry. The method exhibited mean recoveries ranging from 86.2% to 119.7% with relative standard deviations of 0.1–11.3%. The dissipation curve of imazalil during strawberry growth followed the first-order kinetic model with a half-life ranging from 6.5 to 7.1 days. Significant enantioselectivity of imazalil was observed in strawberry grown under field conditions and strawberry wine production process, with enantiomeric fraction values ranging from 0.51 (2 h) to 0.42 (27d) and from 0.48 (0d) to 0.52 (10d), respectively. (+)-imazalil was preferentially degraded in strawberry under field conditions, while (−)-imazalil was preferentially degraded during the fermentation process. The processing factor was lower than 1 for each procedure, indicating that the wine-making process can reduce imazalil residue in strawberry. These findings may facilitate a more accurate risk assessment of imazalil and provide important guidance for the safe and efficacious use of imazalil in agriculture. |
| first_indexed | 2024-03-12T22:23:23Z |
| format | Article |
| id | doaj.art-7a911668f9904b3d815b75f863214078 |
| institution | Directory Open Access Journal |
| issn | 0362-028X |
| language | English |
| last_indexed | 2024-03-12T22:23:23Z |
| publishDate | 2023-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Food Protection |
| spelling | doaj.art-7a911668f9904b3d815b75f8632140782023-07-23T04:53:33ZengElsevierJournal of Food Protection0362-028X2023-01-01861100006Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine productionJia Zhang0Wei Jiang1Zhihang Jia2Wenjie Zhang3Ting Zhang4Meng Wei5Xuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, China; Tongshan Test Station, Xuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221121, ChinaXuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, China; Tongshan Test Station, Xuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221121, ChinaXuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, China; Tongshan Test Station, Xuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221121, ChinaXuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, ChinaXuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, ChinaXuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, China; Tongshan Test Station, Xuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221121, China; Corresponding author at: Xuzhou Institute of Agricultural Sciences of the Xuhuai District of Jiangsu Province, Xuzhou 221000, China.Imazalil is a chiral fungicide widely used to protect strawberries against gray mold, which may pose threats to food safety. This study aims to investigate the stereoselective behavior of imazalil during strawberry growth and strawberry wine production. A method was proposed and validated for the extraction and quantitative analysis of imazalil residues in strawberry, strawberry pomace, and strawberry wine by using ultra-high performance liquid chromatography-tandem mass spectrometry. The method exhibited mean recoveries ranging from 86.2% to 119.7% with relative standard deviations of 0.1–11.3%. The dissipation curve of imazalil during strawberry growth followed the first-order kinetic model with a half-life ranging from 6.5 to 7.1 days. Significant enantioselectivity of imazalil was observed in strawberry grown under field conditions and strawberry wine production process, with enantiomeric fraction values ranging from 0.51 (2 h) to 0.42 (27d) and from 0.48 (0d) to 0.52 (10d), respectively. (+)-imazalil was preferentially degraded in strawberry under field conditions, while (−)-imazalil was preferentially degraded during the fermentation process. The processing factor was lower than 1 for each procedure, indicating that the wine-making process can reduce imazalil residue in strawberry. These findings may facilitate a more accurate risk assessment of imazalil and provide important guidance for the safe and efficacious use of imazalil in agriculture.http://www.sciencedirect.com/science/article/pii/S0362028X22000059ImazalilProcessing factorStereoselective behaviorStrawberry |
| spellingShingle | Jia Zhang Wei Jiang Zhihang Jia Wenjie Zhang Ting Zhang Meng Wei Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production Journal of Food Protection Imazalil Processing factor Stereoselective behavior Strawberry |
| title | Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production |
| title_full | Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production |
| title_fullStr | Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production |
| title_full_unstemmed | Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production |
| title_short | Stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production |
| title_sort | stereoselective behavior and residues of the imazalil during strawberry growth and strawberry wine production |
| topic | Imazalil Processing factor Stereoselective behavior Strawberry |
| url | http://www.sciencedirect.com/science/article/pii/S0362028X22000059 |
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