Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide

This work was focused on the applicability of a new diamide N,N-dimethyl- N,N-dioctylsuccinamide (DMDOSA) employing cyclohexane as the diluent to extract Dy(III) and Sm(III) from nitric acid solutions. The extraction from HNO3 was investigated by distributionmeasurements. The stoichiometry of the pr...

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Main Authors: ZHANG ZHENWEI, LI YEXIN, SUN SIXIU, SUN GUOXIN, CUI YU
Format: Article
Language:English
Published: Serbian Chemical Society 2005-02-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.yu/HtDocs/SHD/vol70/No2/JSCS_V70_No2-09.pdf
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author ZHANG ZHENWEI
LI YEXIN
SUN SIXIU
SUN GUOXIN
CUI YU
author_facet ZHANG ZHENWEI
LI YEXIN
SUN SIXIU
SUN GUOXIN
CUI YU
author_sort ZHANG ZHENWEI
collection DOAJ
description This work was focused on the applicability of a new diamide N,N-dimethyl- N,N-dioctylsuccinamide (DMDOSA) employing cyclohexane as the diluent to extract Dy(III) and Sm(III) from nitric acid solutions. The extraction from HNO3 was investigated by distributionmeasurements. The stoichiometry of the predominant adducts of DMDOSA with HNO3 is 1:1 (HNO3 .DMDOSA) under the studied conditions. The effect of the concentrations of nitric acid, lithium nitrate and extractant on the distribution ratio was investigated. An IR spectral study was also made of the extracted species.
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spelling doaj.art-7ac903d7115c4f0babdc1e84102357862022-12-21T19:01:30ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392005-02-01702223229Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamideZHANG ZHENWEILI YEXINSUN SIXIUSUN GUOXINCUI YUThis work was focused on the applicability of a new diamide N,N-dimethyl- N,N-dioctylsuccinamide (DMDOSA) employing cyclohexane as the diluent to extract Dy(III) and Sm(III) from nitric acid solutions. The extraction from HNO3 was investigated by distributionmeasurements. The stoichiometry of the predominant adducts of DMDOSA with HNO3 is 1:1 (HNO3 .DMDOSA) under the studied conditions. The effect of the concentrations of nitric acid, lithium nitrate and extractant on the distribution ratio was investigated. An IR spectral study was also made of the extracted species.http://www.shd.org.yu/HtDocs/SHD/vol70/No2/JSCS_V70_No2-09.pdfNN-dimethyl-NN-dioctylsuccinamidesynthesisextractionDy(III)Sm(III).
spellingShingle ZHANG ZHENWEI
LI YEXIN
SUN SIXIU
SUN GUOXIN
CUI YU
Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
Journal of the Serbian Chemical Society
N
N-dimethyl-N
N-dioctylsuccinamide
synthesis
extraction
Dy(III)
Sm(III).
title Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
title_full Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
title_fullStr Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
title_full_unstemmed Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
title_short Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
title_sort extraction of dy iii and sm iii with n n dimethyl n n dioctylsuccinamide
topic N
N-dimethyl-N
N-dioctylsuccinamide
synthesis
extraction
Dy(III)
Sm(III).
url http://www.shd.org.yu/HtDocs/SHD/vol70/No2/JSCS_V70_No2-09.pdf
work_keys_str_mv AT zhangzhenwei extractionofdyiiiandsmiiiwithnndimethylnndioctylsuccinamide
AT liyexin extractionofdyiiiandsmiiiwithnndimethylnndioctylsuccinamide
AT sunsixiu extractionofdyiiiandsmiiiwithnndimethylnndioctylsuccinamide
AT sunguoxin extractionofdyiiiandsmiiiwithnndimethylnndioctylsuccinamide
AT cuiyu extractionofdyiiiandsmiiiwithnndimethylnndioctylsuccinamide