Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide
This work was focused on the applicability of a new diamide N,N-dimethyl- N,N-dioctylsuccinamide (DMDOSA) employing cyclohexane as the diluent to extract Dy(III) and Sm(III) from nitric acid solutions. The extraction from HNO3 was investigated by distributionmeasurements. The stoichiometry of the pr...
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Serbian Chemical Society
2005-02-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.shd.org.yu/HtDocs/SHD/vol70/No2/JSCS_V70_No2-09.pdf |
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author | ZHANG ZHENWEI LI YEXIN SUN SIXIU SUN GUOXIN CUI YU |
author_facet | ZHANG ZHENWEI LI YEXIN SUN SIXIU SUN GUOXIN CUI YU |
author_sort | ZHANG ZHENWEI |
collection | DOAJ |
description | This work was focused on the applicability of a new diamide N,N-dimethyl- N,N-dioctylsuccinamide (DMDOSA) employing cyclohexane as the diluent to extract Dy(III) and Sm(III) from nitric acid solutions. The extraction from HNO3 was investigated by distributionmeasurements. The stoichiometry of the predominant adducts of DMDOSA with HNO3 is 1:1 (HNO3 .DMDOSA) under the studied conditions. The effect of the concentrations of nitric acid, lithium nitrate and extractant on the distribution ratio was investigated. An IR spectral study was also made of the extracted species. |
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institution | Directory Open Access Journal |
issn | 0352-5139 |
language | English |
last_indexed | 2024-12-21T13:57:00Z |
publishDate | 2005-02-01 |
publisher | Serbian Chemical Society |
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series | Journal of the Serbian Chemical Society |
spelling | doaj.art-7ac903d7115c4f0babdc1e84102357862022-12-21T19:01:30ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392005-02-01702223229Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamideZHANG ZHENWEILI YEXINSUN SIXIUSUN GUOXINCUI YUThis work was focused on the applicability of a new diamide N,N-dimethyl- N,N-dioctylsuccinamide (DMDOSA) employing cyclohexane as the diluent to extract Dy(III) and Sm(III) from nitric acid solutions. The extraction from HNO3 was investigated by distributionmeasurements. The stoichiometry of the predominant adducts of DMDOSA with HNO3 is 1:1 (HNO3 .DMDOSA) under the studied conditions. The effect of the concentrations of nitric acid, lithium nitrate and extractant on the distribution ratio was investigated. An IR spectral study was also made of the extracted species.http://www.shd.org.yu/HtDocs/SHD/vol70/No2/JSCS_V70_No2-09.pdfNN-dimethyl-NN-dioctylsuccinamidesynthesisextractionDy(III)Sm(III). |
spellingShingle | ZHANG ZHENWEI LI YEXIN SUN SIXIU SUN GUOXIN CUI YU Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide Journal of the Serbian Chemical Society N N-dimethyl-N N-dioctylsuccinamide synthesis extraction Dy(III) Sm(III). |
title | Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide |
title_full | Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide |
title_fullStr | Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide |
title_full_unstemmed | Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide |
title_short | Extraction of Dy(III) and Sm(III) with N,N-dimethyl-N,N-dioctylsuccinamide |
title_sort | extraction of dy iii and sm iii with n n dimethyl n n dioctylsuccinamide |
topic | N N-dimethyl-N N-dioctylsuccinamide synthesis extraction Dy(III) Sm(III). |
url | http://www.shd.org.yu/HtDocs/SHD/vol70/No2/JSCS_V70_No2-09.pdf |
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