Mullite porous ceramics with high strength for high-temperature thermal insulation

To address the low thermal efficiency and serious energy consumption of industrial kilns, the gel casting method is used herein for the successful preparation of porous mullite thermal insulation materials with good thermal and mechanical properties. The effects of poly-γ-glutamic acid (γ-PGA) conte...

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Main Authors: Yameng Wan, Xiang Li, Junying Ma
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785423027370
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author Yameng Wan
Xiang Li
Junying Ma
author_facet Yameng Wan
Xiang Li
Junying Ma
author_sort Yameng Wan
collection DOAJ
description To address the low thermal efficiency and serious energy consumption of industrial kilns, the gel casting method is used herein for the successful preparation of porous mullite thermal insulation materials with good thermal and mechanical properties. The effects of poly-γ-glutamic acid (γ-PGA) content (0.6–2.2 wt%) on the performances of the slurries, green bodies, and sintered bodies are comprehensively investigated based on the gelation mechanism. The mullite slurries show good flowability and stability, and the powders are evenly dispersed. Furthermore, the green bodies have sufficiently high mechanical strengths to meet the conditions of processing into complex shapes. The sample open porosity is shown to increase, and the pore size gradually becomes more uniform, as the γ-PGA content is increased. At a γ-PGA content of 1.8 wt%, the open porosity reaches 75.85 %, the compressive strength is 14.02 MP. The thermal conductivity increases from 0.263 W/(m⋅K) to 0.544 W/(m⋅K) as the temperature increases from 25 °C to 1000 °C. At the same time, the Gong model accurately describes the relationship between the thermal conductivity and porosity. In addition, infrared thermographic analysis and alcohol lamp ablation experiments macroscopically demonstrate the excellent thermal insulation performance of the porous mullite at high temperatures.
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spelling doaj.art-7ad1a356115e4c6e89541ffb292477d92024-02-21T05:27:14ZengElsevierJournal of Materials Research and Technology2238-78542023-11-012756925700Mullite porous ceramics with high strength for high-temperature thermal insulationYameng Wan0Xiang Li1Junying Ma2School of Chemistry and Chemical Engineering, Henan University of Science and Technology, Luoyang, 471023, China; Corresponding author.School of Material Science and Engineering, Zhengzhou University, NO.100 Science Avenue, Zhengzhou, 450001, ChinaSchool of Chemistry and Chemical Engineering, Henan University of Science and Technology, Luoyang, 471023, China; Corresponding author.To address the low thermal efficiency and serious energy consumption of industrial kilns, the gel casting method is used herein for the successful preparation of porous mullite thermal insulation materials with good thermal and mechanical properties. The effects of poly-γ-glutamic acid (γ-PGA) content (0.6–2.2 wt%) on the performances of the slurries, green bodies, and sintered bodies are comprehensively investigated based on the gelation mechanism. The mullite slurries show good flowability and stability, and the powders are evenly dispersed. Furthermore, the green bodies have sufficiently high mechanical strengths to meet the conditions of processing into complex shapes. The sample open porosity is shown to increase, and the pore size gradually becomes more uniform, as the γ-PGA content is increased. At a γ-PGA content of 1.8 wt%, the open porosity reaches 75.85 %, the compressive strength is 14.02 MP. The thermal conductivity increases from 0.263 W/(m⋅K) to 0.544 W/(m⋅K) as the temperature increases from 25 °C to 1000 °C. At the same time, the Gong model accurately describes the relationship between the thermal conductivity and porosity. In addition, infrared thermographic analysis and alcohol lamp ablation experiments macroscopically demonstrate the excellent thermal insulation performance of the porous mullite at high temperatures.http://www.sciencedirect.com/science/article/pii/S2238785423027370MulliteRheological propertiesGreen body propertiesHigh open porosityThermal insulation
spellingShingle Yameng Wan
Xiang Li
Junying Ma
Mullite porous ceramics with high strength for high-temperature thermal insulation
Journal of Materials Research and Technology
Mullite
Rheological properties
Green body properties
High open porosity
Thermal insulation
title Mullite porous ceramics with high strength for high-temperature thermal insulation
title_full Mullite porous ceramics with high strength for high-temperature thermal insulation
title_fullStr Mullite porous ceramics with high strength for high-temperature thermal insulation
title_full_unstemmed Mullite porous ceramics with high strength for high-temperature thermal insulation
title_short Mullite porous ceramics with high strength for high-temperature thermal insulation
title_sort mullite porous ceramics with high strength for high temperature thermal insulation
topic Mullite
Rheological properties
Green body properties
High open porosity
Thermal insulation
url http://www.sciencedirect.com/science/article/pii/S2238785423027370
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AT xiangli mulliteporousceramicswithhighstrengthforhightemperaturethermalinsulation
AT junyingma mulliteporousceramicswithhighstrengthforhightemperaturethermalinsulation