Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell

In this prelimnary work, the aim was to fabricate a simple tin (II) sulfide (SnS) quantum dot-sensitized solar cell (QDSSC) from aqueous solution. The SnS QDSSCs were characterized by using current-voltage test (I-V test), scanning electron microscopy (SEM), and ultraviolet-visible (UV-Vis) spectros...

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Main Authors: Ngoi Kok Kwong, Jun Hieng Kiat
Format: Article
Language:English
Published: De Gruyter 2019-01-01
Series:Green Processing and Synthesis
Subjects:
Online Access:https://doi.org/10.1515/gps-2019-0012
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author Ngoi Kok Kwong
Jun Hieng Kiat
author_facet Ngoi Kok Kwong
Jun Hieng Kiat
author_sort Ngoi Kok Kwong
collection DOAJ
description In this prelimnary work, the aim was to fabricate a simple tin (II) sulfide (SnS) quantum dot-sensitized solar cell (QDSSC) from aqueous solution. The SnS QDSSCs were characterized by using current-voltage test (I-V test), scanning electron microscopy (SEM), and ultraviolet-visible (UV-Vis) spectroscopy. SEM results showed the presence of TiO2 and SnS elements in the sample, confirming the successful synthesis of SnS quantum dots (QDs). The overall efficiency of QDSSCs increased when concentration of the precursor solutions, which were aqueous sodium sulfide and tin (II) sulfate decreased from 0.5 M to 0.05 M. On the other hand, for a fixed precursor concentration, the efficiency of QDSSC reduced once an optimal cycle of of successive ionic layer adsorption and reaction (SILAR) was achieved. The bandgap energies of QDs obtained by extrapolating the Tauc plot were used to predict the QDs size. In general, the QD size was bigger for samples prepared from precursor concentration of 0.5 M, and with higher number of SILAR cycle used. The best performance was obtained from sample prepared from 0.05 M precursor concentration with 4 SILAR cycles.
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spelling doaj.art-7af7fe54b7914863a7ea07014f450a2b2022-12-21T18:22:46ZengDe GruyterGreen Processing and Synthesis2191-95502019-01-018144345010.1515/gps-2019-0012gps-2019-0012Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cellNgoi Kok Kwong0Jun Hieng Kiat1Department of Mechanical and Material Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Bandar Sg. Long, 43000 Kajang, Kajang, MalaysiaDepartment of Mechanical and Material Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Bandar Sg. Long, 43000 Kajang, Kajang, MalaysiaIn this prelimnary work, the aim was to fabricate a simple tin (II) sulfide (SnS) quantum dot-sensitized solar cell (QDSSC) from aqueous solution. The SnS QDSSCs were characterized by using current-voltage test (I-V test), scanning electron microscopy (SEM), and ultraviolet-visible (UV-Vis) spectroscopy. SEM results showed the presence of TiO2 and SnS elements in the sample, confirming the successful synthesis of SnS quantum dots (QDs). The overall efficiency of QDSSCs increased when concentration of the precursor solutions, which were aqueous sodium sulfide and tin (II) sulfate decreased from 0.5 M to 0.05 M. On the other hand, for a fixed precursor concentration, the efficiency of QDSSC reduced once an optimal cycle of of successive ionic layer adsorption and reaction (SILAR) was achieved. The bandgap energies of QDs obtained by extrapolating the Tauc plot were used to predict the QDs size. In general, the QD size was bigger for samples prepared from precursor concentration of 0.5 M, and with higher number of SILAR cycle used. The best performance was obtained from sample prepared from 0.05 M precursor concentration with 4 SILAR cycles.https://doi.org/10.1515/gps-2019-0012quantum dot-sensitized solar cellsnssilarbandgap
spellingShingle Ngoi Kok Kwong
Jun Hieng Kiat
Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell
Green Processing and Synthesis
quantum dot-sensitized solar cell
sns
silar
bandgap
title Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell
title_full Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell
title_fullStr Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell
title_full_unstemmed Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell
title_short Study of fabrication of fully aqueous solution processed SnS quantum dot-sensitized solar cell
title_sort study of fabrication of fully aqueous solution processed sns quantum dot sensitized solar cell
topic quantum dot-sensitized solar cell
sns
silar
bandgap
url https://doi.org/10.1515/gps-2019-0012
work_keys_str_mv AT ngoikokkwong studyoffabricationoffullyaqueoussolutionprocessedsnsquantumdotsensitizedsolarcell
AT junhiengkiat studyoffabricationoffullyaqueoussolutionprocessedsnsquantumdotsensitizedsolarcell