Crystal Structure of Na3MoCl6
The ternary chloride Na3MoCl6 is obtained as red crystals from a disproportionation reaction of molybdenum dichloride, {Mo6}Cl12, in an acidic NaCl/AlCl3 melt at 350 °C. The crystal structure (trigonal, P-31c, a = 687.1(1), c = 1225.3(2) pm, Z = 2, V = 501,0(1) 106 pm3) is that of Na3CrCl6: within a...
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| Format: | Article |
| Language: | English |
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MDPI AG
2011-07-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/1/3/99 |
| _version_ | 1798003694489305088 |
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| author | Martin Beran Gerd Meyer |
| author_facet | Martin Beran Gerd Meyer |
| author_sort | Martin Beran |
| collection | DOAJ |
| description | The ternary chloride Na3MoCl6 is obtained as red crystals from a disproportionation reaction of molybdenum dichloride, {Mo6}Cl12, in an acidic NaCl/AlCl3 melt at 350 °C. The crystal structure (trigonal, P-31c, a = 687.1(1), c = 1225.3(2) pm, Z = 2, V = 501,0(1) 106 pm3) is that of Na3CrCl6: within a hexagonal closest-packing of chloride ions two thirds of the octahedral voids are filled between the AB double layers with Na+/Mo3+, and between the BA layers with Na+. |
| first_indexed | 2024-04-11T12:12:57Z |
| format | Article |
| id | doaj.art-7b1b3aa7a3224212be56a47ea1284436 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T12:12:57Z |
| publishDate | 2011-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-7b1b3aa7a3224212be56a47ea12844362022-12-22T04:24:34ZengMDPI AGCrystals2073-43522011-07-01139910310.3390/cryst1030099Crystal Structure of Na3MoCl6Martin BeranGerd MeyerThe ternary chloride Na3MoCl6 is obtained as red crystals from a disproportionation reaction of molybdenum dichloride, {Mo6}Cl12, in an acidic NaCl/AlCl3 melt at 350 °C. The crystal structure (trigonal, P-31c, a = 687.1(1), c = 1225.3(2) pm, Z = 2, V = 501,0(1) 106 pm3) is that of Na3CrCl6: within a hexagonal closest-packing of chloride ions two thirds of the octahedral voids are filled between the AB double layers with Na+/Mo3+, and between the BA layers with Na+.http://www.mdpi.com/2073-4352/1/3/99molybdenumchloridesodiumsynthesiscrystal structure |
| spellingShingle | Martin Beran Gerd Meyer Crystal Structure of Na3MoCl6 Crystals molybdenum chloride sodium synthesis crystal structure |
| title | Crystal Structure of Na3MoCl6 |
| title_full | Crystal Structure of Na3MoCl6 |
| title_fullStr | Crystal Structure of Na3MoCl6 |
| title_full_unstemmed | Crystal Structure of Na3MoCl6 |
| title_short | Crystal Structure of Na3MoCl6 |
| title_sort | crystal structure of na3mocl6 |
| topic | molybdenum chloride sodium synthesis crystal structure |
| url | http://www.mdpi.com/2073-4352/1/3/99 |
| work_keys_str_mv | AT martinberan crystalstructureofna3mocl6 AT gerdmeyer crystalstructureofna3mocl6 |