Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate
The reaction of manganese(II) sulfate and 2-aminopyrazine affords the title salt, [Mn(H2O)6][Mn(C4H5N3)2(H2O)4](SO4)2·2H2O. The metal atoms in the tetraaqua-coordinated and hexaaqua-coordinated cations lie on centers of inversion in octahedral geometries. The cations, anions and solvent...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809045322 |
| _version_ | 1819105030130630656 |
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| author | Seik Weng Ng Shan Gao Li-Hua Huo |
| author_facet | Seik Weng Ng Shan Gao Li-Hua Huo |
| author_sort | Seik Weng Ng |
| collection | DOAJ |
| description | The reaction of manganese(II) sulfate and 2-aminopyrazine affords the title salt, [Mn(H2O)6][Mn(C4H5N3)2(H2O)4](SO4)2·2H2O. The metal atoms in the tetraaqua-coordinated and hexaaqua-coordinated cations lie on centers of inversion in octahedral geometries. The cations, anions and solvent water molecules are linked by O—H...O, N—H...O and O—H...N hydrogen bonds into a three-dimensional network. |
| first_indexed | 2024-12-22T02:15:46Z |
| format | Article |
| id | doaj.art-7b1d7afb37be4aea9b7b5ff89743e444 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:15:46Z |
| publishDate | 2009-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7b1d7afb37be4aea9b7b5ff89743e4442022-12-21T18:42:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1504m150410.1107/S1600536809045322Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrateSeik Weng NgShan GaoLi-Hua HuoThe reaction of manganese(II) sulfate and 2-aminopyrazine affords the title salt, [Mn(H2O)6][Mn(C4H5N3)2(H2O)4](SO4)2·2H2O. The metal atoms in the tetraaqua-coordinated and hexaaqua-coordinated cations lie on centers of inversion in octahedral geometries. The cations, anions and solvent water molecules are linked by O—H...O, N—H...O and O—H...N hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536809045322 |
| spellingShingle | Seik Weng Ng Shan Gao Li-Hua Huo Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate Acta Crystallographica Section E |
| title | Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate |
| title_full | Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate |
| title_fullStr | Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate |
| title_full_unstemmed | Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate |
| title_short | Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-κN4)manganese(II) disulfate dihydrate |
| title_sort | hexaaquamanganese ii tetraaquabis 2 aminopyrazine amp 954 n4 manganese ii disulfate dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809045322 |
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