High conductive hybrid polymer CsH5(PO4)2-Butvar compounds

Hybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis...

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Main Authors: Gus’kov Rostislav, Ponomareva Valentina
Format: Article
Language:English
Published: EDP Sciences 2021-01-01
Series:MATEC Web of Conferences
Online Access:https://www.matec-conferences.org/articles/matecconf/pdf/2021/09/matecconf_rkfm2021_01041.pdf
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author Gus’kov Rostislav
Ponomareva Valentina
author_facet Gus’kov Rostislav
Ponomareva Valentina
author_sort Gus’kov Rostislav
collection DOAJ
description Hybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis method was determined. The crystal structure of CsH5(PO4)2 (P21/c) remains unchanged in the polymer system. The thickness of the electrolyte is no more than 50-100 μm. Proton conductivity increases by 2 orders of magnitude and depends on the composition. The highest conductivity was 10-1 S/cm at 135 °C. Changes in conductivity are caused by dispersion of the salt, as well as by the presence of insignificant amounts of residual water under the synthesis conditions.
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spelling doaj.art-7b349073c3664b22867a367b3f9a777f2022-12-21T20:21:29ZengEDP SciencesMATEC Web of Conferences2261-236X2021-01-013400104110.1051/matecconf/202134001041matecconf_rkfm2021_01041High conductive hybrid polymer CsH5(PO4)2-Butvar compoundsGus’kov RostislavPonomareva ValentinaHybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis method was determined. The crystal structure of CsH5(PO4)2 (P21/c) remains unchanged in the polymer system. The thickness of the electrolyte is no more than 50-100 μm. Proton conductivity increases by 2 orders of magnitude and depends on the composition. The highest conductivity was 10-1 S/cm at 135 °C. Changes in conductivity are caused by dispersion of the salt, as well as by the presence of insignificant amounts of residual water under the synthesis conditions.https://www.matec-conferences.org/articles/matecconf/pdf/2021/09/matecconf_rkfm2021_01041.pdf
spellingShingle Gus’kov Rostislav
Ponomareva Valentina
High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
MATEC Web of Conferences
title High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
title_full High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
title_fullStr High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
title_full_unstemmed High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
title_short High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
title_sort high conductive hybrid polymer csh5 po4 2 butvar compounds
url https://www.matec-conferences.org/articles/matecconf/pdf/2021/09/matecconf_rkfm2021_01041.pdf
work_keys_str_mv AT guskovrostislav highconductivehybridpolymercsh5po42butvarcompounds
AT ponomarevavalentina highconductivehybridpolymercsh5po42butvarcompounds