High conductive hybrid polymer CsH5(PO4)2-Butvar compounds
Hybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
EDP Sciences
2021-01-01
|
Series: | MATEC Web of Conferences |
Online Access: | https://www.matec-conferences.org/articles/matecconf/pdf/2021/09/matecconf_rkfm2021_01041.pdf |
_version_ | 1818871792357343232 |
---|---|
author | Gus’kov Rostislav Ponomareva Valentina |
author_facet | Gus’kov Rostislav Ponomareva Valentina |
author_sort | Gus’kov Rostislav |
collection | DOAJ |
description | Hybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis method was determined. The crystal structure of CsH5(PO4)2 (P21/c) remains unchanged in the polymer system. The thickness of the electrolyte is no more than 50-100 μm. Proton conductivity increases by 2 orders of magnitude and depends on the composition. The highest conductivity was 10-1 S/cm at 135 °C. Changes in conductivity are caused by dispersion of the salt, as well as by the presence of insignificant amounts of residual water under the synthesis conditions. |
first_indexed | 2024-12-19T12:28:33Z |
format | Article |
id | doaj.art-7b349073c3664b22867a367b3f9a777f |
institution | Directory Open Access Journal |
issn | 2261-236X |
language | English |
last_indexed | 2024-12-19T12:28:33Z |
publishDate | 2021-01-01 |
publisher | EDP Sciences |
record_format | Article |
series | MATEC Web of Conferences |
spelling | doaj.art-7b349073c3664b22867a367b3f9a777f2022-12-21T20:21:29ZengEDP SciencesMATEC Web of Conferences2261-236X2021-01-013400104110.1051/matecconf/202134001041matecconf_rkfm2021_01041High conductive hybrid polymer CsH5(PO4)2-Butvar compoundsGus’kov RostislavPonomareva ValentinaHybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis method was determined. The crystal structure of CsH5(PO4)2 (P21/c) remains unchanged in the polymer system. The thickness of the electrolyte is no more than 50-100 μm. Proton conductivity increases by 2 orders of magnitude and depends on the composition. The highest conductivity was 10-1 S/cm at 135 °C. Changes in conductivity are caused by dispersion of the salt, as well as by the presence of insignificant amounts of residual water under the synthesis conditions.https://www.matec-conferences.org/articles/matecconf/pdf/2021/09/matecconf_rkfm2021_01041.pdf |
spellingShingle | Gus’kov Rostislav Ponomareva Valentina High conductive hybrid polymer CsH5(PO4)2-Butvar compounds MATEC Web of Conferences |
title | High conductive hybrid polymer CsH5(PO4)2-Butvar compounds |
title_full | High conductive hybrid polymer CsH5(PO4)2-Butvar compounds |
title_fullStr | High conductive hybrid polymer CsH5(PO4)2-Butvar compounds |
title_full_unstemmed | High conductive hybrid polymer CsH5(PO4)2-Butvar compounds |
title_short | High conductive hybrid polymer CsH5(PO4)2-Butvar compounds |
title_sort | high conductive hybrid polymer csh5 po4 2 butvar compounds |
url | https://www.matec-conferences.org/articles/matecconf/pdf/2021/09/matecconf_rkfm2021_01041.pdf |
work_keys_str_mv | AT guskovrostislav highconductivehybridpolymercsh5po42butvarcompounds AT ponomarevavalentina highconductivehybridpolymercsh5po42butvarcompounds |