{N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II)
In the title compound, [Zn(NCS)2(C10H15N3)], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN5 trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811019945 |
| _version_ | 1819290658308882432 |
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| author | Xian-Wen Li |
| author_facet | Xian-Wen Li |
| author_sort | Xian-Wen Li |
| collection | DOAJ |
| description | In the title compound, [Zn(NCS)2(C10H15N3)], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN5 trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, molecules are linked by N—H...S hydrogen bonds, generating [100] chains. |
| first_indexed | 2024-12-24T03:26:14Z |
| format | Article |
| id | doaj.art-7b3d72627fd44d549ff9017f0f723b97 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:26:14Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7b3d72627fd44d549ff9017f0f723b972022-12-21T17:17:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m829m82910.1107/S1600536811019945{N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II)Xian-Wen LiIn the title compound, [Zn(NCS)2(C10H15N3)], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN5 trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, molecules are linked by N—H...S hydrogen bonds, generating [100] chains.http://scripts.iucr.org/cgi-bin/paper?S1600536811019945 |
| spellingShingle | Xian-Wen Li {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II) Acta Crystallographica Section E |
| title | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_full | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_fullStr | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_full_unstemmed | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_short | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_sort | n methyl n amp 8242 1 pyridin 2 yl ethylidene ethane 1 2 diamine amp 954 3n n amp 8242 n amp 8242 amp 8242 bis thiocyanato amp 954 n zinc ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811019945 |
| work_keys_str_mv | AT xianwenli nmethylnamp82421pyridin2ylethylideneethane12diamineamp9543nnamp8242namp8242amp8242bisthiocyanatoamp954nzincii |